The potential of calcium oxide nanocatalyst from chicken eggshells for biodiesel production using chicken fat waste

被引:3
|
作者
Rahmayanti, Maya [1 ]
Fatimah, Is [2 ]
Ikhsani, Atika Yahdiyani [1 ]
Azizah, Divya Nur [1 ]
机构
[1] UIN Sunan Kalijaga Yogyakarta, Chem Dept, Yogyakarta 55281, Indonesia
[2] Univ Islam Indonesia, Chem Dept, Kampus Terpadu UII Jl Kaliurang Km 14, Sleman 55584, Yogyakarta, Indonesia
关键词
Biodiesel; Chicken fat waste; Nanocatalyst; Calcium oxide; Eggshell; OIL; CATALYST;
D O I
10.1016/j.inoche.2024.112604
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This research aims to synthesize biodiesel using raw materials from chicken fat waste and a catalyst from eggshells (EGS). The eggshells used as a catalyst were calcined (EGS_calcined) and uncalcined (EGS_uncalcined). The calcination process was carried out at a temperature of 900 degrees C with a heating rate of 5 degrees C/minute under static air conditions for 24 h. The X-ray Diffraction diffractogram showed that the calcination process has successfully converted the calcium carbonate compound in the eggshell into calcium oxide. The particle sizes of EGS_uncalcined and EGS_calcined catalysts were 509.2 nm and 2.9 nm, respectively. Chicken fat transesterification reaction conditions were optimized to increase biodiesel yield, including variations in EGS catalyst mass (1-3 % of chicken fat extract (oil) weight), oil and methanol mole ratio (1:5-1:30), temperature (55-75 degrees C), and reaction time (30-180 min). The EGS catalyst mass conditions, oil and methanol mole ratio, temperature, and reaction time that produced the highest yield (93 %) were 1.5 % (w/w oil), 1:10, 65 degrees C, and 120 min, respectively. Research showed that the calcined EGS_catalyst performs better than the uncalcined EGS_catalyst.
引用
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页数:9
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