High-pressure-high-temperature phase diagram of tin

被引:4
作者
Freville, Robin [1 ,2 ]
Dewaele, Agnes [1 ,2 ]
Guignot, Nicolas [3 ]
Faure, Philippe [4 ]
Henry, Laura [1 ,2 ,3 ]
Garbarino, Gaston [5 ]
Mezouar, Mohamed [5 ]
机构
[1] CEA, DAM, DIF, F-91297 Arpajon, France
[2] Univ Paris Saclay, CEA, Lab Matiere Condit Extremes, F-91680 Bruyeres Le Chatel, France
[3] Synchrotron Soleil, Orme Merisiers, F-91190 St Aubin, France
[4] CEA, DAM, VALDUC, F-21120 Is Sur Tille, France
[5] European Synchrotron Radiat Facil, BP220, F-38043 Grenoble, France
关键词
High pressure engineering - Pyrometers - Pyrometry;
D O I
10.1103/PhysRevB.109.104116
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The high-pressure-high-temperature behavior of tin has been measured with x-ray diffraction and laser-heated diamond anvil cells up to 225 GPa at 300 K and to 110 GPa and <^>4000 K. Temperature has been measured using conventional point pyrometry as well as a four-color mapping pyrometer. The stability fields of Sn liquid and solid phases (beta-Sn, bct gamma -Sn, bcc-Sn, hcp-Sn) have been constrained. The high-pressure hcp-Sn phase has been observed but at higher pressure than under hydrostatic compression. The bcc-bct transition conditions are measured, up to a bcc-bct-liquid triple point at 18.9 GPa/1410 K. A lower bound for bcc-Sn melting line is proposed (Simon equation): Tm = 581((P - 2.86)/6.44 + 1)0.71 (P in GPa, Tm in Kelvin).
引用
收藏
页数:11
相关论文
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