Investigation of nano-confinement effects on asphaltenic crude oil phase behavior in tight and shale reservoirs: Modeling using CPA-EOS

As a result of strong molecule-molecule and molecule-wall interactions, phase behavior in confined fluids differs significantly from that in bulk fluids. Asphaltene precipitation is a challenging issue for both conventional and unconventional (nano-scale) porous media. In this study, a new model based on cubic-plus-association equation of state (CPA-EOS) was developed for studying phase behavior of asphaltenic crude oil and asphaltene precipitation in nanoporous media. The developed model considers confinement phenomena including shift in the critical properties of components, high capillary pressure, and adsorption/desorption of fluid components on rock surface. For this purpose, necessary modifications were performed on both the EOS and phase equilibria calculations. The developed model was then used to analyze two-phase (vapor-liquid) and three-phase (vapor-liquid-asphaltene) behavior in confined systems. Results demonstrated that confinement phenomena shrink the two-phase envelope and shift the critical point of the mixture. It is also shown that instability of asphaltene in the solution is higher in nanoporous media and increases with reducing pore size. Therefore, the amount of precipitated asphaltene in nanoporous media is higher than that in conventional systems. As adsorption of components with higher molecular weights is more than that of low-molecular weight compounds, the crude oil sample is enriched with lighter components and hence, due to adsorption, bubble point pressure increases, upper branch of dew point curve shifts downward and its lower branch shifts upward, and asphaltene instability increases. Neglecting confinement phenomena results in overestimation or underestimation of saturation pressures as well as asphaltene upper and lower onset points and the proposed model can be of high importance in predicting the extent of asphaltene precipitation during natural depletion or solvent injection in tight oil reservoirs.