CaO -catalyzed trans-esterification of brassica carinata seed oil for biodiesel production

被引:0
作者
Mekuriaw, Tsegaye Abera [1 ]
Abera, Metadel Kassahun [2 ]
机构
[1] Woldia Univ, Woldia Inst Technol, Sch Chem & Mech Engn, Woldia, Ethiopia
[2] Bahir Dar Univ, Bahir Dar Inst Technol, Fac Chem & Food Engn, Bahir Dar, Ethiopia
关键词
Brassica carinata seed oil; CaO; Tran-sesterification; Biodiesel; Fuel properties; CRAMBE-ABYSSINICA; VEGETABLE-OILS; ENERGY; PERFORMANCE; MICROALGAE; EMISSIONS; BIOFUELS; CYCLE; CROP;
D O I
10.1016/j.heliyon.2024.e33790
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Brassica carinata seed is a non-edible oil containing crop grown for oil-based product development like biodiesel synthesis. However, recently technical challenges such as availability of feedstock, type of catalyst, cost, and quality of biodiesel hindered the feasibility and utilization of biodiesel. Thus, this study addressed those problems under the production of fatty acid methyl ester through trans-esterification reaction in the presence of heterogeneous catalyst (CaO), and methanol alcohol from Ethiopian brassica carinata seed oil. The synergetic and antagonistic effects of selected parameters (temperature, methanol to oil molar ratio, and amount of catalyst) on the yield of FAME were analyzed. Box-Behnken response surface methodology statistical analysis was applied to examine the parametric interaction effect, and optimization of reaction conditions. Accordingly, 90 % of fatty acid methyl ester (FAME) yield was achieved at the optimum value of 65 degrees C temperature, 14.85: 1 methanol to oil molar ratio, and 13.77 % catalyst load. The fuel properties of the resulted biodiesel were determined following standard procedures, and the results were within the standard limits (ASTM D6751). This implies that brassica carinata oil over heterogeneous catalyzed reaction medium under optimum reaction conditions provides higher biodiesel yield.
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页数:15
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