Effect of annealing temperature on the structural, morphological, compositional, and optical characteristics of CNCTS thin films for solar cells

被引：1
作者：
Abali, Abdelaziz [1 ]
El Kissani, Abdelkader [1 ]
Drissi, Safia [1 ]
Haj, Dris Ait el [1 ]
Elmassi, Said [1 ]
Nkhaili, Lahcen [1 ]
EL Assali, Kassem [1 ]
机构：
[1] Cadi Ayyad Univ, Fac Sci Semlalia, Lab Mat Energy & Environm LaMEE, POB 2390, Marrakech 40000, Morocco
来源：
PHYSICA B-CONDENSED MATTER | 2024年 / 690卷
关键词：
Quinary; Cu; 2; Ni; 0.75; Co; 0.25; SnS; 4; Spin-coating; Sulfurization; NiSnS; CoSnS; CU2NISNS4; NANOPARTICLES; ELECTRICAL-PROPERTIES; CU2COSNS4; FILMS;
D O I：
10.1016/j.physb.2024.416243
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The compound Cu 2 Ni 0.75 Co 0.25 SnS 4 (CNCTS) was synthesized using the spin-coating technique. Analysis via Xray diffraction and Raman spectroscopy revealed the formation of a cubic structure at 350 degrees C, with a lattice parameter of 5.40 & Aring; and a crystallite size of 51 A degrees , with no secondary phase detected. Scanning electron microscopy and energy dispersive spectroscopy examination showed that the annealed CNCTS sample at 350 degrees C for 1 h displayed surface morphologies that were nearly uniform, dense, and rough, with a composition close to stoichiometric. UV -Visible -Near infrared analysis indicated that the bandgap energy of the annealed CNCTS at 350 degrees C is 1.39 eV, rendering it highly suitable for low-cost photovoltaic applications.
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页数：6
相关论文
共 32 条
[1]   Effect of secondary phases controlled by precursor composition on the efficiency of CZTS thin film solar cell [J].
Agrawal, Sagar ;
De Souza, Danilo Oliveira ;
Balasubramanian, C. ;
Mukherjee, Subroto .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2024, 267
[2]   Preparation and characterization of Cu2CoSnS4 thin films for solar cells via co-electrodeposition technique: Effect of electrodeposition time [J].
Beraich, M. ;
Taibi, M. ;
Guenbour, A. ;
Zarrouk, A. ;
Boudalia, M. ;
Bellaouchou, A. ;
Tabyaoui, M. ;
Mansouri, S. ;
Sekkat, Z. ;
Fahoume, M. .
OPTIK, 2019, 193
[3]   Studies on the electrical properties of Cu2NiSnS4 thin films prepared by a simple chemical method [J].
Bitri, N. ;
Dridi, S. ;
Chaabouni, F. ;
Abaab, M. .
MATERIALS LETTERS, 2018, 213 :31-34
[4]   Quaternary Cu2NiSnS4 thin films as a solar material prepared through electrodeposition [J].
Chen, Hui-Ju ;
Fu, Sheng-Wen ;
Tsai, Tsung-Chieh ;
Shih, Chuan-Feng .
MATERIALS LETTERS, 2016, 166 :215-218
[5]   Synthesis of quaternary Cu2NiSnS4 thin films as a solar energy material prepared through "spray" technique [J].
Dridi, S. ;
Bitri, N. ;
Abaab, M. .
MATERIALS LETTERS, 2017, 204 :61-64
[6]   Substitution effects on physical and chemical properties of Cu2Fe1-xCoxSnS4 thin films synthesized by the sol-gel technique [J].
Drissi, S. ;
EL Kissani, A. ;
Abali, A. ;
Lhaj, D. Ait ;
Elmassi, S. ;
Amiri, L. ;
Nkhaili, L. ;
EL Assali, K. ;
Narjis, A. ;
Outzourhit, A. .
PHYSICA B-CONDENSED MATTER, 2023, 667
[7]   Structural and transport properties of Cu2CoSnS4 films prepared by spray pyrolysis [J].
El Khouja, Outman ;
Assahsahi, Ilhame ;
Nouneh, Khalid ;
Touhami, Mohamed Ebn ;
Secu, Mihail ;
Talbi, Abdelali ;
Khaaissa, Yassine ;
Matei, Elena ;
Stancu, Viorica ;
Galatanu, Andrei ;
Galca, Aurelian Catalin .
CERAMICS INTERNATIONAL, 2022, 48 (21) :32418-32426
[8]   Structural, optical and electrical properties of Cu2CoSnS4 thin film solar cells prepared by facile sol-gel route br [J].
El Kissani, A. ;
Elhaj, D. Ait ;
Drissi, S. ;
Abali, A. ;
Agdad, A. ;
Dads, H. Ait ;
Nkhaili, L. ;
El Mansouri, A. ;
Chaib, H. ;
El Assali, K. ;
Outzourhit, A. .
THIN SOLID FILMS, 2022, 758
[9]  
Elhaj D.A., 2021, Synthese et caracterisation de nouveaux materiaux absorbeurs a base de Cu2NiSnS4 pour la conversion photovoltaique, P140
[10]   Development of Cu2NiSnS4 based thin film solar cells without a sulfurization step [J].
Elhaj, D. Ait ;
El Kissani, A. ;
Elyaagoubi, M. ;
Dads, H. Ait ;
Welatta, F. ;
Nkhaili, L. ;
Chaib, H. ;
Outzourhit, A. .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2020, 107
1234