Cellulose acetate, a source from discarded cigarette butts for the development of mixed matrix loose nanofiltration membranes for selective separation

被引:3
|
作者
Gohain, Moucham Borpatra
Karki, Sachin
Ingole, Pravin G. [1 ]
机构
[1] CSIR North East Inst Sci & Technol, Engn Sci & Technol Div, Chem Engn Grp, Jorhat 785006, Assam, India
关键词
Cigarette butts; Cellulose acetate; GO andCOOH-TiO2 nanoparticles; Mixed matrix loose nanofiltration membranes; Dyes and salts separation; HOLLOW-FIBER MEMBRANES; GRAPHENE OXIDE; TRANSPORT-PROPERTIES; ANTIBACTERIAL; FILM; COMPOSITE; NANOPARTICLES; PERFORMANCE; REMOVAL; FILTER;
D O I
10.1016/j.ijbiomac.2024.132197
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
This study presents an environmentally friendly method for extracting cellulose acetate (CA) from discarded cigarette filters, which is then utilized in the fabrication of cellulose -based membranes designed for high flux and rejection rates. CA membranes are likeable to separate dyes and ions, but their separation efficiency is exposed when the contaminant concentration is very low. So, we have integrated graphene oxide (GO) and carboxylated titanium dioxide (COOH-TiO 2 ) in CA to develop mixed matrix membranes (MMMs) and studied them against dyes and most used salts. The CA has been extracted from these butts and added GO and COOH-TiO 2 nanoparticles to develop MMMs. The present work administers the effective separation of five dyes (methyl orange, methyl violet, methylene blue, cresol red, and malachite green) and salts (NaCl and Na 2 SO 4 ) along with the high efficiency of water flux by prepared CA membranes. The prepared membranes rejected up to 94.94 % methyl violet, 91.28 % methyl orange, 88.28 % methylene blue, 89.91 % cresol red, and 91.70 % malachite green dye. Along with the dyes, the membranes showed -40.40 % and - 42.97 % rejection of NaCl and Na 2 SO 4 salts, respectively. Additionally, these membranes have tensile strength up to 1.54 MPa. Various characterization techniques were performed on all prepared CA membranes to comprehend their behaviour. The antibacterial activity of MMMs was investigated using the Muller -Hinton -Disk diffusion method against the gram -positive bacterium Staphylococcus aureus (S. aureus) and the gram -negative bacterium Escherichia coli (E. coli) . We believe the present work is an approach to utilizing waste materials into valuable products for environmental care.
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页数:16
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