Chemical route synthesis of nanohybrid MoO 3-rGO for high-performance hybrid supercapacitors

被引:10
作者
Dilwale, Ganesh V. [1 ]
Piao, Guanghai [2 ]
Kim, Hansol [2 ]
Pawar, Anuradha C. [3 ]
Said, Zafar [4 ,6 ]
Nimat, Rajesh K. [5 ]
Kim, Ji Man [2 ]
Bulakhe, Ravindra N. [2 ]
机构
[1] RNC Arts JDB Commerce & NSC Sci Coll, Dept Phys, Nashik Rd, Nasik 422101, MS, India
[2] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea
[3] KK Wagh Inst Engn Educ & Res, Dept Appl Sci & Maths, Nasik 422003, MS, India
[4] Univ Sharjah, Dept Sustainable & Renewable Energy Engn, POB 27272, Sharjah, U Arab Emirates
[5] Balasaheb Desai Coll, Dept Phys, Patan 415206, MS, India
[6] Lebanese Amer Univ LAU, Dept Ind & Mech Engn, Byblos, Lebanon
基金
新加坡国家研究基金会;
关键词
Hybrid supercapacitor; Nanocomposite; Energy density; Hexagonal microrods; Metal oxide; GRAPHENE OXIDE; ASYMMETRIC SUPERCAPACITOR; ENHANCED PERFORMANCE; COMPOSITE FILMS; CARBON; NANOSHEET; NANOPARTICLES; ELECTRODE;
D O I
10.1016/j.est.2024.112050
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Asymmetric Hybrid supercapacitor (AHS) is distinguished by a combination of electrostatic and electrochemical storage mechanisms. High performance of AHS is based on MoO 3 (MO) hybridized with reduced graphene oxide (rGO). In the present study, a single step hydrothermal method was used to synthesise MO and MoO 3 -rGO (MOG) nanohybrid materials. MO and MOG samples were then used to prepare electrodes. These electrodes were subjected to CV, GCD, and EIS analyses with three- and two -electrode systems. Results showed that the MOG-2 composite achieved a higher specific capacity of 607.82 C g -1 than bare MO at 96 C g -1 at a sweep rate of 2 mVs - 1 in the three -electrode system. Thus, rGO can effectively enhance active sites for redox reactions. At current density of 1 A g -1 , the MOG//rGO had the highest specific capacity of 188.40 C g -1 . Based on GCD evaluation, the HSC coin cell device had a maximum energy density of 36.78 Whkg - 1 and a power density 2546.84 Wkg - 1 and the device retained 87.6 % capacity after 10,000 cycles.
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页数:11
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