Density and Viscosity of the Mixtures of Dimethylsulfoxide with Choline Chloride/Ethylene Glycol Eutectic Solvent

被引：0

作者：

Yu, Jinxiang ^{[1
]}

Chen, Xiangyu ^{[1
]}

Wang, Xiaopo ^{[1
]}

机构：

[1] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermo Fluid Sci & Engn, Minist Educ, Xian 710049, Peoples R China

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2024年 / 53卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Density; Dimethylsulfoxide; Choline chloride/ethylene glycol solvent; Viscosity; PLUS ETHYLENE-GLYCOL; BINARY-MIXTURES; PHYSICOCHEMICAL PROPERTIES; REFRACTIVE-INDEXES; AQUEOUS MIXTURES; CHLORIDE; TEMPERATURE; CONDUCTIVITY; SULFOXIDE;

D O I：

10.1007/s10953-024-01402-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The density and viscosity of the pseudo-binary mixtures of eutectic solvent (ES) composed of choline chloride and ethylene glycol ([ChCl/EG]) with dimethylsulfoxide (DMSO) were measured. In order to understand the effect of the mole ratio of ChCl:EG, two ChCl/EG ESs with the mole ratio of 1:3 and 1:4 (abbreviated as [ChCl/EG](1:3) and [ChCl/EG](1:4) in this work) were prepared. The measurements were carried out by digital vibrating U-tube density meter and Ubbelohde capillary viscometer from 303.15 to 323.15 K at atmospheric pressure (98.5 kPa). The Jouyban-Acree model was applied to correlate the experimental density and viscosity data of DMSO/[ChCl/EG](1:3) and DMSO/[ChCl/EG](1:4) mixtures. In addition, based on the experimental data, the derived properties of the mixtures, such as excess molar volume and viscosity deviation, were calculated. The comparison and analysis of excess molar volume and viscosity deviation for DMSO/[ChCl/EG](1:2) reported in literature and the results obtained in this work were carried out.

引用

页码：1617 / 1632

页数：16

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