Brightly Luminescent and Color-Tunable CsPbBr3 Nanocrystals with Enhanced Stability and Room Temperature Cubic Structure through Codoping with MnCl2

被引:0
作者
Darwish, Elshaimaa [1 ]
Elia, Jack [1 ]
Fehn, Dominik [2 ]
Koellner, David [3 ]
Pourjafar, Amir [4 ]
Christiansen, Silke [4 ]
Meyer, Karsten [2 ]
Webber, Kyle Grant [3 ]
Brabec, Christoph J. [1 ,5 ]
Batentschuk, Miroslaw [1 ]
Osvet, Andres [1 ]
机构
[1] Friedrich Alexander Univ Erlangen Nurnberg, Mat Elect & Energy Technol I MEET, Martensstr 7, D-91058 Erlangen, Germany
[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Dept Chem & Pharm, Inorgan Chem, D-91058 Erlangen, Germany
[3] Inst Glass & Ceram, Dept Mat Sci & Engn, Martensstr 5, D-91058 Erlangen, Germany
[4] Fraunhofer Inst Ceram Technol & Syst IKTS, Correlat Microscopy & Mat Data Dept, IKTS Aussere Nurnberger Str 62, D-91301 Forchheim, Germany
[5] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Immerwahrstr 2, D-91058 Erlangen, Germany
关键词
light conversion; perovskite nanoparticle; semiconductor quantum dots; LEAD HALIDE PEROVSKITES; LIGHT-EMITTING-DIODES; QUANTUM-DOT; SOLAR-CELLS; EFFICIENT; PHASE; FORMAMIDINIUM; TRANSITION; EMISSION; CSPBX3;
D O I
10.1002/adem.202302213
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lead halide perovskites have attracted much attention from the scientific community in recent years due to their attractive properties and their proven potential in many applications. Nevertheless, their stability and lead toxicity have remained a problem. Herein, the potential of manganese as a divalent dopant to offer better stability and replace a fraction of the toxic lead ions is investigated. Moreover, the reverse microemulsion method is used to obtain tunability in emission and bandgap by doping cesium lead bromide. Furthermore, cubic cesium lead bromide particles are managed to obtain at room temperature as a result of doping.
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页数:10
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