A high strength and high electrical conductivity copper based composite enhanced by graphene and Al 2 O 3 nanoparticles

被引:9
作者
Song, Hongyi [1 ]
Mai, Junjie [2 ,3 ]
Zhang, Zequan [2 ]
Gu, Anping [4 ]
Mai, Yongjin [2 ,3 ]
Chang, Yongqin [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Peoples R China
[3] Adv Met Mat & Forming Engn Technol Res Ctr Guangdo, Guangzhou 510006, Peoples R China
[4] Shanghai Nucl Engn Res & Design Inst, Shanghai 200233, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2024年 / 899卷
基金
中国国家自然科学基金;
关键词
Copper matrix composite; Graphene; Electrical conductivity; Tensile strength; MECHANICAL-PROPERTIES; DEFORMATION-BEHAVIOR; INTERNAL OXIDATION; MICROSTRUCTURE; NANOCOMPOSITES; GROWTH;
D O I
10.1016/j.msea.2024.146432
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The rapid development of electrical and electronic engineering requires to further surmount the trade-off between the electrical conductivity and strength of Cu matrix composite. In this study, the surface of Cu - Al 2 O 3 powder is selective for carbon sources, and only alpha-naphthol can prepare graphene. Graphene and Al 2 O 3 particles are simultaneously incorporated into Cu matrix by hot-press sintering Cu - Al 2 O 3 powders by internal oxidation coated with in-situ grown graphene. This composite exhibits a good combination of strength and conductivity (600 MPa of ultimate tensile strength and 81.7 % IACS of electrical conductivity) due to synergistic effect of graphene and Al 2 O 3 particles. This composite fabricated by such synergistic more effectively retains the microstructure induced by plastic deformation during the cold-rolling process. Both graphene and Al 2 O 3 particles uniformly distribute in Cu matrix. Coherent Al 2 O 3 particles and graphene in situ grown can be well enhance to Orowan looping mechanism effect, and the addition of graphene in Cu matrix composite with Al 2 O 3 particles can improve dislocation strengthening and dispersion strengthening at the same time. Our study provides an effective route to achieve simultaneously high strength and conductivity of Cu matrix composites.
引用
收藏
页数:9
相关论文
共 30 条
[21]   Fabrication of Cu-Al2O3 Composites by Simplified Internal Oxidation Process [J].
Tian, Baohong ;
Xia, Chengdong ;
Jia, Shuguo .
MANUFACTURING PROCESSES AND SYSTEMS, PTS 1-2, 2011, 148-149 :416-419
[22]   Role of Hydrogen in Chemical Vapor Deposition Growth of Large Single-Crystal Graphene [J].
Vlassiouk, Ivan ;
Regmi, Murari ;
Fulvio, Pasquale F. ;
Dai, Sheng ;
Datskos, Panos ;
Eres, Gyula ;
Smirnov, Sergei .
ACS NANO, 2011, 5 (07) :6069-6076
[23]   Direct synthesis of high-quality graphene on Cu powders from adsorption of small aromatic hydrocarbons: A route to high strength and electrical conductivity for graphene/Cu composite [J].
Wang, Miao ;
Wang, Li-Dong ;
Sheng, Jie ;
Yang, Zi-Yue ;
Shi, Zhen-Dong ;
Zhu, Yun-Peng ;
Li, Jie ;
Fei, Wei-Dong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 798 :403-413
[24]   In situ synthesis of TiB2 particulate reinforced copper matrix composite with a rotating magnetic field [J].
Wang, Tongmin ;
Zou, Cunlei ;
Chen, Zongning ;
Li, Mingyu ;
Wang, Wei ;
Li, Rengeng ;
Kang, Huijun .
MATERIALS & DESIGN, 2015, 65 :280-288
[25]   DISLOCATION DENSITIES IN SOME ANNEALED AND COLD-WORKED METALS FROM MEASUREMENTS ON THE X-RAY DEBYE-SCHERRER SPECTRUM [J].
WILLIAMSON, GK ;
SMALLMAN, RE .
PHILOSOPHICAL MAGAZINE, 1956, 1 (01) :34-46
[26]   Microstructural evolution and strengthening mechanisms in cold-rolled Cu-Ag alloys [J].
Xie, Mingwang ;
Huang, Wei ;
Chen, Huiming ;
Gong, Liukui ;
Xie, Weibin ;
Wang, Hang ;
Yang, Bin .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 851
[27]   Hot deformation behavior and microstructure evolution of annealed Al-7.9Zn-2.7Mg-2.0Cu (wt%) alloy [J].
Zang, Qianhao ;
Yu, Huashun ;
Lee, Yun-Soo ;
Kim, Min-Seok ;
Kim, Hyoung-Wook .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 763 :25-33
[28]   Achieving high strength and high ductility in metal matrix composites reinforced with a discontinuous three-dimensional graphene-like network [J].
Zhang, Xiang ;
Shi, Chunsheng ;
Liu, Enzuo ;
He, Fang ;
Ma, Liying ;
Li, Qunying ;
Li, Jiajun ;
Bacsa, Wolfgang ;
Zhao, Naiqin ;
He, Chunnian .
NANOSCALE, 2017, 9 (33) :11929-11938
[29]   Consideration of Orowan strengthening effect in particulate-reinforced metal matrix nanocomposites: A model for predicting their yield strength [J].
Zhang, Z ;
Chen, DL .
SCRIPTA MATERIALIA, 2006, 54 (07) :1321-1326
[30]   Factors controlling the tensile properties of ultrafine structured Cu-5vol%Al2O3 nanocomposite prepared by high energy mechanical milling and powder compact extrusion [J].
Zhou, D. S. ;
Zhang, D. L. ;
Kong, C. ;
Munroe, P. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2013, 584 :67-72