Poly(triphenylamine-thiazolo[5,4-d]thiazole) copolymer dyes with different anchoring end groups: Synthesis, dye-sensitized solar cell (DSSC) performance and femtosecond excited state absorption spectroscopy

In this study, the poly(triphenylaminethiazolo[5,4- d ]thiazole) copolymer dyes having the different anchoring end groups of aldehyde (poly-TPATT-CHO; P5), sulfonic acid (poly-TPATT-SO 3 H; P5S) and cyanoacrylic acid (poly-TPATT-COOH; P5C) have been synthesized and used as sensitizers in dye-sensitized solar cells (DSSCs). The effects of the anchoring end groups of the P5, P5S and P5C copolymer dyes on the DSSC performance were examined. The synthesized copolymer dyes were characterized using 1 H NMR, UV - vis. absorption and fluorescence (FL) emission spectroscopy, cyclic voltammetry (CV), MALDI-TOF-MS and FE-SEM-EDS methods. Among the studied polymers, the P5C polymer dye exhibited the best photovoltaic performance with a J SC of 6.46 mA cm -2 , a V OC of 0.667 V, a FF of 0.70, and an overall power conversion efficiency (PCE) of 3.02 % under standard AM 1.5 G solar light conditions. These results are attributed to the strong binding ability of cyanoacrylic acid to the TiO 2 , leading to a greater photocurrent and hindered charge recombination. The effect of electron transfer mechanisms of the polymers on the DSSC performance have been investigated using the femtosecond transient absorption (fs TA) spectroscopy. The DSSC performance of the poly(triphenylaminethiazolo[5,4- d ]thiazole) increased greatly by the presence of the cyanoacrylic acid anchoring end group in P5C polymer dye. The fs TA spectroscopy results revealed the presence of singlet - triplet transition for the P5C copolymer dye, while the P5 and P5S copolymers showed only singlet - singlet transitions. The observed triplet state transition in the P5C polymer increased the yield of the DSSC system.