Completing the Ba-As Compositional Space: Synthesis and Characterization of Three New Binary Zintl Arsenides, Ba3As4, Ba5As4, and Ba16As11

Three novel binary barium arsenides, Ba3As4, Ba5As4, and Ba16As11, were synthesized and their crystal and electronic structures were investigated. Structural data collected via the single-crystal X-ray diffraction method indicate that the anionic substructures of all three novel compounds are composed of structural motifs based on the homoatomic As-As contacts, with [As-2](4-) dimers found in Ba5As4 and Ba16As11, and an [As-4](6-) tetramer found in Ba3As4. Ba3As4 and Ba5As4 crystallize in the orthorhombic crystal system-with the non-centrosymmetric space group Fdd2 (a = 15.3680(20) & Aring;, b = 18.7550(30) & Aring;, c = 6.2816(10) & Aring;) for the former, and the centrosymmetric space group Cmce (a = 16.8820(30) & Aring;, b = 8.5391(16) & Aring;, and c = 8.6127(16) & Aring;) for the latter-adopting Eu3As4 and Eu5As4 structure types, respectively. The heavily disordered Ba16As11 structure was solved in the tetragonal crystal system with the space group P(sic)42(1)m (a = 12.8944(12) & Aring; and c = 11.8141(17) & Aring;). The Zintl concept can be applied to each of these materials as follows: Ba3As4 = (Ba2+)(3)[As-4](6-), Ba5As4 = (Ba2+)(5)(As3-)(2)[As-2](4-), and 2 x Ba16As11 = (Ba2+)(32)(As3-) approximate to (20)[As-2](4-) approximate to 1, pointing to the charge-balanced nature of these compounds. Electronic structure calculations indicate narrow bandgap semiconducting behavior, with calculated bandgaps of 0.47 eV for Ba3As4, 0.34 eV for Ba5As4, and 0.33 eV for Ba16As11.