Unveiling the potential of amorphous nanocatalysts in membrane-based hydrogen production

Hydrogen, as a clean and renewable energy source, is a promising candidate to replace fossil fuels and alleviate the environmental crisis. Compared with the traditional H-type cells with a finite-gap, the design of membrane electrodes can reduce the gas transmission resistance, enhance the current density, and improve the efficiency of hydrogen production. However, the harsh environment in the electrolyser makes the membrane electrode based water electrolysis technology still limited by the lack of catalyst activity and stability under the working conditions. Due to the abundant active sites and structural flexibility, amorphous nanocatalysts are alternatives. In this paper, we review the recent research progress of amorphous nanomaterials as electrocatalysts for hydrogen production by electrolysis at membrane electrodes, illustrate and discuss their structural advantages in membrane electrode catalytic systems, as well as explore the significance of the amorphous structure for the development of membrane electrode systems. Finally, the article also looks at future opportunities and adaptations of amorphous catalysts for hydrogen production at membrane electrodes. The authors hope that this review will deepen the understanding of the potential of amorphous nanomaterials for application in electrochemical hydrogen production, facilitating future nanomaterials research and new sustainable pathways for hydrogen production. This review presents the progress of amorphous nanocatalysts in membrane electrode based electrocatalytic hydrogen production, in which the modulating of morphology, composition and phase of amorphous nanomaterials are systematically discussed.