Utilizing Cs-TPA/Ce-KIT-6 solid-acid catalyst for enhanced biodiesel production from almond and amla oil feedstocks

被引:3
作者
Ganesan, Sivarasan [1 ]
Manikandan, Velu [2 ,3 ]
Albeshr, Mohammed F. [4 ]
Dixit, Saurav [5 ,6 ]
Song, Kwang Soup [2 ]
Lo, Huang-Mu [1 ]
机构
[1] Chaoyang Univ Technol, Dept Environm Engn & Management, Taichung, Taiwan
[2] Kumoh Natl Inst Technol, Dept Med IT Convergence Engn, Gumi, South Korea
[3] Saveetha Univ, Dept Conservat Dent & Endodont, Saveetha Dent Coll & Hosp, Saveetha Inst Med & Tech Sci SIMATS, Chennai 600077, Tamilnadu, India
[4] King Saud Univ, Coll Sci, Dept Zool, POB 2455, Riyadh 11451, Saudi Arabia
[5] Lovely Profess Univ, Div Res & Dev, Phagwara 144411, Punjab, India
[6] Peter Great St Petersburg Polytech Univ, St Petersburg 195251, Russia
基金
新加坡国家研究基金会;
关键词
Transesterification; Esterification; Mesoporous; Solid-acid catalysts; Hydrothermal synthesis; OLEIC-ACID; MESOPOROUS SILICATE; CESIUM SALTS; FATTY-ACIDS; ESTERIFICATION; METHANOL; TRANSESTERIFICATION; HETEROPOLYACIDS; DEHYDRATION; GLYCEROL;
D O I
10.1016/j.psep.2024.02.082
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study focuses on the synthesis and characterization of Cs-tungstophosphoric acid/Ce-KIT-6 (Cs-TPA/CK), Cssilicotungstic acid/Ce-KIT-6 (Cs-STA/CK), and Ni-Zn/Ce-KIT-6 (Ni-Zn/CK) catalysts for biodiesel production from almond and amla oil feedstocks. The synthesized catalysts underwent comprehensive characterization utilizing XRD, BET surface area analysis, SEM, and TEM techniques, confirming the successful incorporation of Ce 3 + , Cs-TPA, Cs-STA, and Ni-Zn units into the KIT-6 framework. Among the catalysts tested, Cs-TPA/CK exhibited the highest biodiesel conversion rates, reaching 98% for oleic acid and 96 -98% for non-edible oils (almond and amla oil). Additionally, the recyclability of the catalysts was evaluated, demonstrating sustained catalytic activity for up to five cycles. These findings underscore the potential of Cs-TPA/CK as a highly efficient catalyst for biodiesel production from both edible and non-edible oil sources, with promising implications for sustainable energy production.
引用
收藏
页码:256 / 266
页数:11
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