Utilizing Cs-TPA/Ce-KIT-6 solid-acid catalyst for enhanced biodiesel production from almond and amla oil feedstocks

被引:3
作者
Ganesan, Sivarasan [1 ]
Manikandan, Velu [2 ,3 ]
Albeshr, Mohammed F. [4 ]
Dixit, Saurav [5 ,6 ]
Song, Kwang Soup [2 ]
Lo, Huang-Mu [1 ]
机构
[1] Chaoyang Univ Technol, Dept Environm Engn & Management, Taichung, Taiwan
[2] Kumoh Natl Inst Technol, Dept Med IT Convergence Engn, Gumi, South Korea
[3] Saveetha Univ, Dept Conservat Dent & Endodont, Saveetha Dent Coll & Hosp, Saveetha Inst Med & Tech Sci SIMATS, Chennai 600077, Tamilnadu, India
[4] King Saud Univ, Coll Sci, Dept Zool, POB 2455, Riyadh 11451, Saudi Arabia
[5] Lovely Profess Univ, Div Res & Dev, Phagwara 144411, Punjab, India
[6] Peter Great St Petersburg Polytech Univ, St Petersburg 195251, Russia
基金
新加坡国家研究基金会;
关键词
Transesterification; Esterification; Mesoporous; Solid-acid catalysts; Hydrothermal synthesis; OLEIC-ACID; MESOPOROUS SILICATE; CESIUM SALTS; FATTY-ACIDS; ESTERIFICATION; METHANOL; TRANSESTERIFICATION; HETEROPOLYACIDS; DEHYDRATION; GLYCEROL;
D O I
10.1016/j.psep.2024.02.082
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study focuses on the synthesis and characterization of Cs-tungstophosphoric acid/Ce-KIT-6 (Cs-TPA/CK), Cssilicotungstic acid/Ce-KIT-6 (Cs-STA/CK), and Ni-Zn/Ce-KIT-6 (Ni-Zn/CK) catalysts for biodiesel production from almond and amla oil feedstocks. The synthesized catalysts underwent comprehensive characterization utilizing XRD, BET surface area analysis, SEM, and TEM techniques, confirming the successful incorporation of Ce 3 + , Cs-TPA, Cs-STA, and Ni-Zn units into the KIT-6 framework. Among the catalysts tested, Cs-TPA/CK exhibited the highest biodiesel conversion rates, reaching 98% for oleic acid and 96 -98% for non-edible oils (almond and amla oil). Additionally, the recyclability of the catalysts was evaluated, demonstrating sustained catalytic activity for up to five cycles. These findings underscore the potential of Cs-TPA/CK as a highly efficient catalyst for biodiesel production from both edible and non-edible oil sources, with promising implications for sustainable energy production.
引用
收藏
页码:256 / 266
页数:11
相关论文
共 57 条
  • [1] Synthesis and photoluminescence of Ca-(Sn,Ti)-Si-O compounds
    Abe, Shunsuke
    Yamane, Hisanori
    Yoshida, Hisashi
    [J]. MATERIALS RESEARCH BULLETIN, 2010, 45 (04) : 367 - 372
  • [2] Enhancing kinetics of biodiesel production using morpholine
    Bala, Dharshini D.
    Chidambaram, Dev
    [J]. CATALYSIS COMMUNICATIONS, 2016, 83 : 48 - 52
  • [3] Conversion of a variety of high free fatty acid containing feedstock to biodiesel using solid acid supported catalyst
    Bala, Dharshini D.
    de Souza, Kimberley
    Misra, Mano
    Chidambaram, Dev
    [J]. JOURNAL OF CLEANER PRODUCTION, 2015, 104 : 273 - 281
  • [4] Single step esterification of algae oil using mesoporous solid acid catalyst
    Bala, Dharshini D.
    Misra, Mano
    Chidambaram, Dev
    [J]. FUEL, 2014, 117 : 1093 - 1095
  • [5] Quadruple Anionic Buckybowls by Solid-State Chemistry of Corannulene and Cesium
    Bauert, Tobias
    Zoppi, Laura
    Koller, Georg
    Siegel, Jay S.
    Baldridge, Kim K.
    Ernst, Karl-Heinz
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (34) : 12857 - 12860
  • [6] ANALYSIS OF NITROGEN ADSORPTION ISOTHERMS ON POROUS AND NONPOROUS SILICAS BY BET AND ALPHAS METHODS
    BHAMBHANI, MR
    TURK, DH
    SING, KSW
    CUTTING, PA
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1972, 38 (01) : 109 - +
  • [7] Esterification of free fatty acids with methanol using heteropolyacids immobilized on silica
    Caetano, C. S.
    Fonseca, I. M.
    Ramos, A. M.
    Vital, J.
    Castanheiro, J. E.
    [J]. CATALYSIS COMMUNICATIONS, 2008, 9 (10) : 1996 - 1999
  • [8] Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
    Cavuoto, Denise
    Zaccheria, Federica
    Ravasio, Nicoletta
    [J]. CATALYSTS, 2020, 10 (11) : 1 - 26
  • [9] Surface-appropriate lipophobicity - Application in isobutene oligomerization over Teflon-modified silica-supported 12-silicotungstic acid
    Chen, Guifang
    Li, Jing
    Yang, Xiangguang
    Wu, Yue
    [J]. APPLIED CATALYSIS A-GENERAL, 2006, 310 : 16 - 23
  • [10] Comparative studies of Zr-based MCM-41 and MCM-48 mesoporous molecular sieves:: Synthesis and physicochemical properties
    Chen, L. F.
    Zhou, X. L.
    Norena, L. E.
    Wang, J. A.
    Navarrete, J.
    Salas, P.
    Montoya, A.
    Del Angel, P.
    Llanos, M. E.
    [J]. APPLIED SURFACE SCIENCE, 2006, 253 (05) : 2443 - 2451