A novel 1,3-diazepine-based fluorescent probe for highly selective detection of Hg 2+

被引:9
作者
Aisikaer, Ailipire [1 ]
Sa, Min [1 ]
Jin, Yiling [1 ]
Che, Yuanyuan [1 ]
Li, Xiaojuan [1 ]
机构
[1] Xinjiang Normal Univ, Coll Chem & Chem Engn, Xinyi Rd 102, Urumqi 830054, Peoples R China
关键词
1,3-diazepine; Fluorescent probe; Detection of mercury ion; Fluorescence quench; CHEMOSENSOR; SENSOR; ION;
D O I
10.1016/j.dyepig.2024.112170
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel 1,3-diazepine based fluorescent probe for Hg 2 + has been successfully synthesized and characterized. Comprising a furan and pyridine, the probe L1 is a blue-emitting 1,3-diazepine derivative, which transforms into an imine form with high fluorescent yellow-emitting under alkaline conditions. Fluorescence quench of the probe in ethanol was observed with the addition of Hg 2 + aqueous in the presence and absence of other metal ions, with a visible color change from colorless to yellow, and this fluorescence quench can be observed in a wide pH range of 3-11. An important feature for this probe is its high selectivity towards mercury ions for the aqueous-phase detection of Hg 2 + over the other competitive metal ions, making the "naked-eye" detection of mercury ions possible.
引用
收藏
页数:7
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