Structure and properties of the metal-containing monomer based on nickel acrylate and 4 '-phenyl-2,2 ':6 ',2 "-terpyridine for self-healing polymers

被引：2

作者：

Sorin, Evgeny S. ^{[1
]}

Baimuratova, Rose K. ^{[1
]}

Tkachev, Valery V. ^{[1
]}

Utenyshev, Andrey N. ^{[1
]}

Kuzmin, Alexey, V ^{[2
]}

Dzhardimalieva, Gulzhian I. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Moscow 142432, Russia

[2] Russian Acad Sci, Inst Solid State Phys, Chernogolovka, 142432, Moscow, Russia

[3] Natl Res Univ, Moscow Aviat Inst, Moscow 125993, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 03期

关键词：

terpyridine; metal acrylates; nickel complexes; unsaturated complexes; crystal structure; self-healing; IN-VITRO; COMPLEXES;

D O I：

10.1016/j.mencom.2024.04.022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new complex of nickel acrylate and 4 ' -phenyl-2,2 ' :6 ' ,2 " - terpyridine, analogs of which have been previously used to obtain self -healing metallopolymers, has been prepared. The complex was analyzed by X-ray diffraction, IR and UV absorption spectroscopy, differential scanning calorimetry and thermogravimetric analysis. The values of effective activation energy of solid -phase polymerization and heat of double bond opening for this complex have been calculated.

引用

页码：382 / 384

页数：3

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