Polyethylene Glycol Nitrite (PEG-ONO) as a Novel Diazotizing Agent

被引：9
作者：
Bochare, Machhindra D. [1 ]
Degani, Mariam S. [1 ]
机构：
[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, NP Marg, Bombay 400019, Maharashtra, India
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 05期
关键词：
Diazotization; Nitrite; PEG; Green chemistry; Safety; SOLVENT-FREE CONDITIONS; AZO-DYES; EFFICIENT SYNTHESIS; DIAZONIUM SALTS; CARBON-DIOXIDE; ARYL AMINES; NANOPARTICLES; REACTIVITY; OXIDATION; STORAGE;
D O I：
10.1021/acssuschemeng.6b03210
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A polyethylene glycol nitrite (PEG-ONO) has been developed as a novel diazotizing agent. It is found to be a cost-effective, highly stable, easy to handle, and efficient diazotizing agent. This reagent has been explored in various well-known reactions occurring via the diazonium intermediate. The nonvolatile nature of PEG ONO reduces its exposure to the user and thereby minimizes the risk of nitrite toxicity.
引用
收藏
页码：3716 / 3720
页数：5
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