Polyethylene Glycol Nitrite (PEG-ONO) as a Novel Diazotizing Agent

被引：9

作者：

Bochare, Machhindra D. ^{[1
]}

Degani, Mariam S. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, NP Marg, Bombay 400019, Maharashtra, India

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 05期

关键词：

Diazotization; Nitrite; PEG; Green chemistry; Safety; SOLVENT-FREE CONDITIONS; AZO-DYES; EFFICIENT SYNTHESIS; DIAZONIUM SALTS; CARBON-DIOXIDE; ARYL AMINES; NANOPARTICLES; REACTIVITY; OXIDATION; STORAGE;

D O I：

10.1021/acssuschemeng.6b03210

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polyethylene glycol nitrite (PEG-ONO) has been developed as a novel diazotizing agent. It is found to be a cost-effective, highly stable, easy to handle, and efficient diazotizing agent. This reagent has been explored in various well-known reactions occurring via the diazonium intermediate. The nonvolatile nature of PEG ONO reduces its exposure to the user and thereby minimizes the risk of nitrite toxicity.

引用

页码：3716 / 3720

页数：5

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