Synthesis of 1-adamantyl-4-alkyl-1 H-1,2,3-triazoles under thermal and microwave conditions

被引：0

作者：

Aminov, Rishat I. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochemi & Catalysis, Ufa Fed Res Ctr, Ufa 450075, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

adamantane; 1,2,3-triazoles; azides; click chemistry; ionic liquids; microwave irradiation; IONIC LIQUIDS; BINOR-S; CYCLOADDITIONS; ALKYLATION; CHEMISTRY; SALTS;

D O I：

10.1016/j.mencom.2024.04.030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aluminate ionic liquid [Et 3 NH] + [Al 2 Cl 7 ] - was found to be an effective catalyst for the reactions of haloadamantanes with trimethylsilyl azide to produce the corresponding azidoadamantanes in 92-98% yields. Using 'click chemistry', the thus obtained azidoadamantanes were reacted with terminal alkynes under thermal or microwave conditions to cleanly afford the expected 1,4-disubstituted 1,2,3-triazoles some of which were new.

引用

页码：406 / 408

页数：3

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