Progress of metal phosphides as the anode materials for sodium ion batteries

被引：15
作者：
He, Liqiang [1 ]
Guo, Jiayang [1 ]
Liu, Shuai [1 ]
Wang, Fei [2 ]
Li, Xiao [1 ]
Su, Zongmin
机构：
[1] Changchun Univ Sci & Technol, Jilin Prov Int Joint Res Ctr Photofunct Mat & Chem, Jilin Prov Sci & Technol Innovat Ctr Opt Mat & Che, Sch Chem & Environm Engn, Changchun 130022, Peoples R China
[2] Yanshan Univ, Coll Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2024年 / 997卷
基金：
中国国家自然科学基金;
关键词：
Metal phosphides; Electrochemical energy storage; Anode; Sodium ion batteries; HIGH-PERFORMANCE ANODE; EXCELLENT CYCLING STABILITY; AT-CARBON NANOCOMPOSITE; LITHIUM-ION; HIGH-CAPACITY; NEGATIVE ELECTRODE; FACILE SYNTHESIS; NICKEL PHOSPHIDE; STABLE ANODE; RED P;
D O I：
10.1016/j.jallcom.2024.174924
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metal phosphide has been recognized as a promising anode material for sodium-ion batteries due to its high theoretical specific capacity and suitable redox potential. However, the challenges such as poor electronic conductivity and large volume expansion of metal phosphide lead to poor cyclic stability of metal phosphide, which limits its practical application. In recent years, metal phosphide with various structure and composition designs have been developed to effectively improve their cyclic stability and reaction kinetics. This review provides a systematic summary of the recent research advancements in metal phosphide anode materials for sodium-ion batteries (SIBs), covering sodium-ion storage mechanisms, synthesis strategies, modification methods, and future challenges and opportunities for further development. The aim of this review is to promote the research on metal phosphide anode materials for expediting the development and application of sodium-ion batteries. In addition, the future development of MPs for SIB anodes is proposed.
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页数：26
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