Hydrogen generation from an alkaline solution of NaBH4 using a Ni-B catalyst supported on hydroxyapatite

被引：7

作者：

Pham, Sy Hieu ^{[1
]}

Phan, Thanh Son ^{[2
]}

Nguyen, Hong Nhung ^{[1
]}

Cong, Hong Hanh ^{[1
]}

Pham, Duy Khanh ^{[1
]}

Nguyen, Nhat Linh ^{[1
]}

Le, Thi Hong Phong ^{[1
]}

Nguyen, Duy Cuong ^{[3
]}

Nguyen, Thi Lan ^{[3
]}

Nguyen, Dinh Lam ^{[2
]}

Phan, Chi M. ^{[4
]}

Hoang, Anh Son ^{[1
,5
]}

机构：

[1] Vietnam Acad Sci & Technol, Inst Mat Sci, 18 Hoang Quoc Viet, Hanoi 10000, Vietnam

[2] Univ Danang, Univ Sci & Technol, Da Nang 550000, Vietnam

[3] Hanoi Univ Sci & Technol, Sch Mat Sci & Engn, Hanoi 100000, Vietnam

[4] Curtin Univ, Discipline Chem Engn, WASM MECE, Perth, WA 6845, Australia

[5] Vietnam Acad Sci & Technol, Grad Univ Sci & Technol, Hanoi 100000, Vietnam

来源：

JOURNAL OF ENERGY STORAGE | 2024年 / 96卷

关键词：

Nickel borane; Hydroxyapatite; Sodium borohydride; Hydrolysis; Hydrogen storage; SODIUM-BOROHYDRIDE SOLUTION; BIMETALLIC COBALT; NICKEL-CATALYSTS; SURFACE-AREA; HYDROLYSIS; EFFICIENT; RU; NANOCOMPOSITES; PERFORMANCE; MECHANISM;

D O I：

10.1016/j.est.2024.112545

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The advancement of a cost-effective, high-efficiency, and reliable catalyst is critical for efficient hydrogen generation from sodium borohydride (NaBH4). In this study, we synthesized hydroxyapatite (HAP) supported NiB at low temperatures using the ion exchange method. The optimize NiB/HAP catalyst exhibits exceptional catalytic performance, achieving a significant hydrogen evolution rate of 4359 mL.g Ni-1.min(-1) from NaBH 4 at 303 K and an impressive activation energy of 53.63 kJ.mol(-1). This performance exceeds that of the majority of previously documented catalysts. In addition, the NiB/HAP catalyst has good reusability, maintaining 75 % of its initial catalytic activity following five performance tests. This catalyst exhibits exceptional performance and can be prepared under simple conditions, making it highly practical for future applications.

引用

页数：12

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