Investigation of electrochemical and photoluminescence properties of Dy 3+doped SrO/BaO/Al 2 O 3 nanocomposite for supercapacitor and display applications

被引:8
作者
Manjunath, L. S. [1 ]
Sridhar, K. N. [2 ]
Manjunatha, H. C. [3 ]
Vidya, Y. S. [4 ]
Munirathnam, R. [5 ]
Deepak, K. [6 ]
Manjunatha, S. [7 ]
Shivanna, M. [8 ]
Kumar, Suman [8 ]
Shivaprasad, M. G. [9 ]
机构
[1] Govt Womens Coll, Dept Phys, Hunsur 571105, Karnataka, India
[2] Govt First Grade Coll, Dept Phys, Malur 563130, Karnataka, India
[3] Govt First Grade Coll, Dept Phys, Devanahalli 562110, Karnataka, India
[4] Lal Bahadur Shastri Govt First Grade Coll, Dept Phys, Bangalore 560032, Karnataka, India
[5] Rajah Serfoji Govt Coll, Dept Phys, Thanjavur 613005, Tamil Nadu, India
[6] REVA Univ, Sch Appl Sci, Dept Phys, Bengaluru 560064, Karnataka, India
[7] BMS Coll Engn, Dept Chem, Bengaluru 560019, Karnataka, India
[8] REVA Univ, Sch Appl Sci, Dept Chem, Bengaluru 560064, Karnataka, India
[9] Govt First Grade Coll, Dept Phys, Chamarajanagar 571313, Karnataka, India
关键词
SBA; Dy; Nanocomposites; Ternary NCs; Supercapacitor; Display devices; Yellow-green emission; LED applications; TERNARY NANOCOMPOSITES; PERFORMANCE; PHOTOCATALYSIS; CATALYST;
D O I
10.1016/j.ceramint.2024.05.052
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The current study investigates the synthesis and characterization of dysprosium -doped strontium barium aluminum nanocomposites (SBAD NCs), aiming to enhance their suitability for display and supercapacitor applications. SBAD NCs are synthesized by Solution combustion synthesis using aloeuera extract as a reducing agent. Multi -phase formation of NCs due to SrO, BaO, and y -Al2O3 phases was confirmed by PXRD analysis, and crystallite size is found to be in the range of 26 nm to 36 nm. SEM analysis confirmed the surface morphology and the elemental composition was affirmed by the EDAX spectrum which confirmed the purity of the synthesis. The blue shift in the UV-visible absorption peak with increasing dopant concentration suggests a rise in the direct energy band gap from 4.07 eV to 4.11 eV. FTIR analysis confirmed functional groups and fingerprint region affirmed the presence of Sr-O, Ba-O, and Al-O bonds. Photoluminescence analysis performed under excitation wavelength 276 nm revealed a prominent emission peak at 565 nm, and the CIE values fall in the yellow -green region of visible spectra. The CCT value was found to be 4490 K-4542 K which might find an application as a nanophosphor in cool light -emitting diodes. The tailored nanocomposites exhibit exceptional electrochemical performance characterized by superior specific capacitance, and improved charge-discharge kinetics, as evaluated through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The specific capacitance is found to be in the range of 103.26 F/g to 173.24 F/g at a scan rate of 10 mV/s with increasing Dy 3+ dopant concentration from 1 mol% to 9 mol% respectively. The dysprosium -doped SBAD NCs emerge as promising candidates for high-performance energy storage systems and vibrant display technologies, offering a synergistic integration of efficient energy storage and vivid display functionalities.
引用
收藏
页码:27520 / 27529
页数:10
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