Na0.4MnO2/MXene nanocomposites as cathodes for high-performance aqueous zinc-ion batteries

The distinctive configuration of MnO2 renders it an exceptionally promising candidate for cathode materials for aqueous zinc-ion batteries (ZIBs). However, its practical utilization is constrained by the sluggish diffusion kinetics of Zn2+ and the capacity degradation resulting from lattice distortions occurring during charge and discharge cycles. To address these challenges, Na0.4MnO2@MXene with a typical 2 x 4 tunnel structure has been successfully synthesized by a simple hydrothermal method in the presence of 5 M NaCl. The nanorods are about 56 nm in diameter. The zinc-ion batteries (ZIBs) with Na0.4MnO2@MXene displays a specific capacity of 324.6 mA h g(-1) at 0.2 A g(-1), and have a high reversible capacity of 153.8 mA h g(-1) after 1000 charge-discharge cycles at 2 A g(-1 )with a capacity retention of 91.4%. The unique morphology endows abundant electrochemical active sites and facile ion diffusion kinetics, that contribute to the high specific capacity and stability. The Na0.4MnO2@MXene with a 2 x 4 tunnel structure is a promising candidate as an electrode material for ZIBs.