Palladium-Catalyzed Three-Component Cascade Carbonylation Reaction to Construct Benzofuran Derivatives

被引：7

作者：

Li, Ming ^{[1
]}

Xu, Shanmei ^{[1
]}

Chen, Dong-Ping ^{[1
]}

Gao, Fan ^{[1
]}

Li, Shun-Xi ^{[1
]}

Zhu, Shuang-Xi ^{[1
]}

Qiu, Yi-Feng ^{[1
]}

Quan, Zheng-Jun ^{[1
]}

Wang, Xi-Cun ^{[1
]}

Liang, Yong-Min ^{[2
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Gansu Int Sci & Technol Cooperat, Base Water Retent Chem Funct Mat, Lanzhou 730070, Gansu, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 11期

基金：

中国国家自然科学基金;

关键词：

COUPLING REACTIONS; ARYL; CYCLIZATION; DIFLUOROALKYLATION; HYDRIDE; IODIDES;

D O I：

10.1021/acs.joc.4c00420

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel three-component cyclization carbonylation reaction of iodoarene-tethered propargyl ethers with amine and CO is reported. This palladium-catalyzed cascade reaction undergoes a sequence of oxidative addition, unsaturated bond migration, carbonyl insertion, and nucleophilic attack to deliver the benzofuran skeleton. Both aromatic amines and aliphatic amines could proceed smoothly in this transformation under one atm of CO.

引用

页码：7741 / 7746

页数：6

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