NMR spectroscopic investigations of transition metal complexes in organometallic and bioinorganic chemistry

被引：13

作者：

Shin, Jeongcheol ^{[1
]}

Lim, Mi Hee ^{[2
]}

Han, Jiyeon ^{[3
]}

机构：

[1] Duksung Womens Univ, Dept Chem, Seoul 01369, South Korea

[2] Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea

[3] Univ Seoul, Dept Appl Chem, Seoul 02504, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2024年 / 45卷 / 07期

基金：

新加坡国家研究基金会;

关键词：

bioinorganic chemistry; metalloproteins; nuclear magnetic resonance spectroscopy; organometallic chemistry; transition metal complexes; NUCLEAR-MAGNETIC-RESONANCE; SPIN-LATTICE-RELAXATION; DIOXIDE COORDINATION CHEMISTRY; H BOND ACTIVATION; CARBON-DIOXIDE; C-13; NMR; STRUCTURAL-CHARACTERIZATION; REDUCTIVE ELIMINATION; CHEMICAL-SHIFTS; PT-195;

D O I：

10.1002/bkcs.12853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The field of coordination chemistry has evolved to intersect with organic chemistry and biochemistry, giving rise to the disciplines of organometallic and bioinorganic chemistry. Nuclear magnetic resonance (NMR) spectroscopy can be applied for characterizing transition metal complexes, spanning both diamagnetic and paramagnetic complexes prevalent in organometallic compounds and metalloproteins. This review offers a comprehensive overview of a wide variety of characterization techniques, ranging from basic 1H and 13C NMR spectroscopy to advanced methods such as heteronuclear experiments, polarization transfer techniques, relaxometry, and multidimensional NMR spectroscopy. The diverse array of NMR spectroscopic methods outlined here promises to enhance our comprehension of transition metal complexes, facilitating the development of innovative catalysts and therapeutics.

引用

页码：593 / 613

页数：21

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