Emerging electrocatalysts for green ammonia production: Recent progress and future outlook

被引:4
作者
Mahmood, Sajid [1 ,2 ]
Iqbal, Shahid [1 ]
Wang, Zeping [1 ]
Ammar, Muhammad [3 ]
Iqbal, Muhammad Javed [4 ]
Bahadur, Ali [5 ,6 ]
Awwad, Nasser S. [7 ]
Ibrahium, Hala A. [8 ]
机构
[1] Univ Nottingham Ningbo China, Nottingham Ningbo China Beacons Excellence Res & I, Ningbo 315100, Peoples R China
[2] Gulf Univ Sci & Technol, Funct Mat Grp, Mishref 32093, Kuwait
[3] Govt Coll Univ, Dept Chem Engn Technol, Faisalabad 38000, Pakistan
[4] Univ Okara, Dept Chem, Renala Khurd, Pakistan
[5] Wenzhou Kean Univ, Coll Sci Math & Technol, Nanomat Res Ctr, Dept Chem, Wenzhou 325060, Zhejiang, Peoples R China
[6] Kean Univ, Dorothy & George Hennings Coll Sci Math & Technol, 1000 Morris Ave, Union, NJ 07083 USA
[7] King Khalid Univ, Fac Sci, Chem Dept, POB 9004, Abha 61413, Saudi Arabia
[8] King Khalid Univ, Fac Sci, Biol Dept, POB 9004, Abha 61413, Saudi Arabia
关键词
Nitrogen reduction; Electrochemical reaction; Electrocatalyst; Nitrogen production rate; Faradaic efficiency; NITROGEN REDUCTION REACTION; HABER-BOSCH PROCESS; ELECTROCHEMICAL SYNTHESIS; AMBIENT CONDITIONS; ATMOSPHERIC-PRESSURE; LOW-TEMPERATURE; N-2; REDUCTION; MOLECULAR NITROGEN; HIGH SELECTIVITY; ACTIVE CATALYST;
D O I
10.1016/j.arabjc.2024.105950
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the Haber-Bosch process (HBp), which uses elevated pressure and temperature to produce more concentration of nitrogen and hydrogen gases, 90% of the 175 million metric tons of NH3 generated worldwide in 2016 were manufactured in this process. According to the road plan for sustainable ammonia production sustainably, using water as a reducing agent is the most effective way to fix nitrogen in close-quarters ambiance. A complete explanation of theoretical and practical work on electrocatalytic nitrogen reduction is provided in this article, with special attention paid to the low selectivity of nitrogen reduction to ammonia in comparison to protons to hydrogen. Since they are essential for accurately achieving high nitrogen production and Faradaic efficiency (FE), their information outlines electrocatalysts, electrolyte selection criteria, and managed experiment design. Under diverse conditions, the evolution of theory and experiment is examined. Finally, feedback is given on this field's present issues and prospects.
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页数:28
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