Structural influences of the substituents of tridentate triazole-based ligands - more than just a minor role in the solid-state structure

被引：1

作者：

Kroos, Simon ^{[1
]}

Hebenbrock, Marian ^{[1
]}

机构：

[1] Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 28-30, D-48149 Munster, Germany

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS | 2024年 / 239卷 / 7-8期

关键词：

tridentate ligands; intermolecular interactions; triazole; morpholine; Hirshfeld surface analysis; COMPLEXES;

D O I：

10.1515/zkri-2024-0069

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

New triazole-based tridentate ligands were synthesized, and their crystal structures determined. Through comparison with the crystal structures of the starting materials and related published ligands, dependencies of intermolecular interactions based on the substitution patterns of the triazole motif were identified. In addition to pi-stacking interactions, hydrogen bonding, and C-H<middle dot><middle dot><middle dot>pi interactions emerged as key players in intermolecular interactions. The observed variations in these interactions will aid in the design of platinum(II) complexes with specific properties.

引用

页码：225 / 237

页数：13