The Use of the Mannich Reaction toward Amino-Based Anthraquinone Applied in Aqueous Redox Flow Battery

被引：0

作者：

Almeida, Renata G. ^{[1
]}

De Silva, Oshadie ^{[2
]}

Delolo, Fabio G. ^{[1
]}

Araujo, Maria H. ^{[1
]}

Maniam, Subashani ^{[2
]}

da Silva Junior, Eufranio N. ^{[1
]}

机构：

[1] Univ Fed Minas Gerais, Dept Quim, Inst Ciencias Exatas, BR-31270901 Belo Horizonte, MG, Brazil

[2] RMIT Univ, STEM Coll, Sch Sci, Appl Chem & Environm Sci, Melbourne, Vic 3001, Australia

来源：

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH | 2024年 / 5卷 / 10期

关键词：

alizarin; anthraquinone; energy storages; Mannich reactions; redox flow batteries; PH; CAPACITY; ELECTROLYTES; QUINONES; LIFETIME;

D O I：

10.1002/aesr.202400118

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A water-soluble anthraquinone derived from alizarin, 3HAAQ, is introduced as the redox-active material in a negative potential electrolyte (anolyte) for aqueous redox flow batteries operating at pH 14. The synthesis of 3HAAQ is carried out using the Mannich reaction, which significantly improves the solubility of the new compound, an important factor for its use in RFB. Pairing with potassium ferri/ferrocyanide positive electrolyte, this flow battery exhibits an open-circuit voltage of 1.24 V and maintains nearly 80% of the theoretical capacity at 40 mA cm-2 current density. A water-soluble anthraquinone derived from alizarin, 3HAAQ, is introduced as the redox-active material in a negative potential electrolyte (anolyte) for aqueous redox flow batteries operating at pH 14image (c) 2024 WILEY-VCH GmbH

引用

页数：8

共 56 条

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