Stability and photoluminescence of Bi doped (La,Y) 2 O 3 phosphor powders

被引:0
作者
Jaffar, Babiker M. [1 ,2 ]
Swart, H. C. [1 ]
Ahmed, H. A. A. Seed [2 ]
Yousif, A. [2 ]
Kroon, R. E. [1 ]
机构
[1] Univ Free State, Dept Phys, Box 339, ZA-9300 Bloemfontein, South Africa
[2] Univ Khartoum, Dept Phys, Box 321, Omdurman 11115, Sudan
基金
新加坡国家研究基金会;
关键词
Bismuth ions; Stability; Photoluminescence; LUMINESCENCE PROPERTIES; SOLID-SOLUTIONS; SYSTEM; ION; TEMPERATURE; BISMUTH; Y2O3; PB2+;
D O I
10.1016/j.materresbull.2024.112950
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
La 2-y Y y O 3 phosphor powders were prepared via the citric acid sol-gel combustion method and their stability was checked after four months of storage in the atmosphere using X-ray diffraction. The material, like La 2 O 3 , was prone to hydroxylation unless a high proportion of Y was added, which also caused changes in the phases present. Based on its stability, the composition La 0.5 Y 1.5 O 3 was selected for further study with Bi doping. The luminescence from this material was not as intense as that from Y 2-x O 3 :Bi x =0.005 , but there was a significant shift in colour as a result of the added La which meant that emission from the Bi 3 + ions at the S 6 sites of the alloy was close to that of unstable La 2 O 3 on the colour chart.
引用
收藏
页数:8
相关论文
共 59 条
  • [1] Photoluminescence, cathodoluminescence degradation and surface analysis of Gd2O3:Bi pulsed laser deposition thin films
    Abdelrehman, M. H. M.
    Kroon, R. E.
    Coetsee, E.
    Yousif, A.
    Ahmed, Hassan A. A. Seed
    Swart, H. C.
    [J]. PHYSICA B-CONDENSED MATTER, 2022, 631
  • [2] Luminescence properties of Yb3+and Er3+co-doped into Gd2O3:Bi3+phosphor powder
    Abdelrehman, Mogahid H. M.
    Kroon, Robin E.
    Yousif, Abdelrhman
    Ahmed, Hassan A. A. Seed
    Swart, Hendrik C.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 902
  • [3] Photoluminescence, thermoluminescence, and cathodoluminescence of optimized cubic Gd2O3:Bi phosphor powder
    Abdelrehman, Mogahid H. M.
    Kroon, Robin E.
    Yousif, Abdelrhman
    Seed Ahmed, Hassan A. A.
    Swart, Hendrik C.
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2020, 38 (06):
  • [4] The binary rare earth oxides
    Adachi, G
    Imanaka, N
    [J]. CHEMICAL REVIEWS, 1998, 98 (04) : 1479 - 1514
  • [5] Allen M Alper., 1995, Phase Diagrams in Advanced Ceramics
  • [6] Crystal chemistry, stability and properties of interlanthanide perovskites: A review
    Artini, Cristina
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2017, 37 (02) : 427 - 440
  • [7] The Bi3+ 6s and 6p electron binding energies in relation to the chemical environment of inorganic compounds
    Awater, Roy H. P.
    Dorenbos, Pieter
    [J]. JOURNAL OF LUMINESCENCE, 2017, 184 : 221 - 231
  • [8] Luminescence and excited state dynamics of Bi3+ centers in Y2O3
    Babin, V.
    Chernenko, K.
    Lipinska, L.
    Mihokova, E.
    Nikl, M.
    Schulman, L. S.
    Shalapska, T.
    Suchocki, A.
    Zazubovich, S.
    Zhydachevskii, Ya.
    [J]. JOURNAL OF LUMINESCENCE, 2015, 167 : 268 - 277
  • [9] INVESTIGATIONS ON BI3+-ACTIVATED PHOSPHORS
    BLASSE, G
    BRIL, A
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (01) : 217 - &
  • [10] BOULON G, 1967, CR ACAD SCI B PHYS, V264, P1747