Molecular enhancement of Cu-based catalysts for CO2 electroreduction

被引：3

作者：

Luo, Haiqiang ^{[1
]}

Li, Bo ^{[1
]}

Ma, Jian-Gong ^{[1
]}

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr,Haihe Lab S, Key Lab Adv Energy Mat Chem,Dept Chem,Frontiers Sc, Tianjin 300071, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 70期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; ELECTROCATALYSTS; ETHYLENE; TECHNOLOGIES; STRATEGIES; ELECTRODES; CONVERSION; CAPTURE;

D O I：

10.1039/d4cc02619e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical carbon dioxide reduction reaction (eCO(2)RR) represents an effective means of achieving renewable energy storage and a supply of carbon-based raw materials. However, there are still great challenges in selectively producing specific hydrocarbon compounds. The unique ability of the copper (Cu) catalyst to promote proton-coupled electron transfer processes offers clear advantages in generating value-added products. This review presents molecular enhancement strategies for Cu-based catalysts for CO2 electroreduction. We also elucidate the principles of each strategy for enhancing eCO(2)RR performance, discuss the structure-activity relationships, and propose some promising molecular enhancement strategies. This review will provide guidance for the development of organic-inorganic hybrid Cu-based catalysts as high-performance CO2 electroreduction catalysts.

引用

页码：9298 / 9309

页数：12

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