Application of Fe3O4 @Carbon/Graphene Oxide Nanocomposites for Cu(II) Removal from Wastewater

被引:1
作者
Wu, Mengya [1 ]
Wu, Riliang [1 ]
Zang, Chuangqi [1 ,2 ]
Yu, Changyuan [3 ]
Liu, Yunfang [1 ]
机构
[1] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China
[2] Beijing Tianhai Ind Co Ltd, Beijing 101109, Peoples R China
[3] Beijing Univ Chem Technol, Sch Life Sci & Technol, Beijing 100029, Peoples R China
关键词
Magnetite nanoparticle; Graphene oxide; Nanocomposite; Cu(2+)removal; Adsorption;
D O I
10.4028/p-309506
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The Cu(2+ )in the drinking water has a very serious impact on human health and social ecology. Many countries have the policy on the Cu2+ concentration limitation in drinking water and the industrial Cu2+ emission standards for the treated wastewater. Scientists have developed many methods to remove Cu2+ from wastewater. Among all the adsorption method is widely used due to its high efficacy, feasibility and low cost. The adsorbent is critical to achieving superior Cu(2+ )removal result. In this paper, Fe3O4/carbon-graphene oxide nanocomposites (Fe3O4@C-GO) were prepared by a hydrothermal method. The Fe3O4@C-GO is the main absorbent to Cu2+ through chemisorption. The specific surface area of Fe3O4@C-GO dramatically increases from 16 m(2)/g of Fe3O4@C to 62 m(2)/g, which expands the Cu2+ absorption capacity up to 350 mg/g. Fe(3)O(4 )nanoparticles with about 12 nm in diameter are uniformly encapsulated in the C-GO matrix, and therefore the Fe3O4@C-GO can be easily separated from the solution via magnetics. This adsorbent is also very easily recovered by an external magnetic field from the treated wastewater and has high reusability.
引用
收藏
页码:41 / 58
页数:18
相关论文
共 61 条
[21]   Polydopamine coated graphene oxide aerogels and their ultrahigh adsorption ability [J].
Huang, Ting ;
Dai, Jian ;
Yang, Jing-hui ;
Zhang, Nan ;
Wang, Yong ;
Zhou, Zuo-wan .
DIAMOND AND RELATED MATERIALS, 2018, 86 :117-127
[22]   Nano-catalytic behavior of highly efficient and regenerable mussel-inspired Fe3O4@CFR@GO and Fe3O4@CFR@TiO2 magnetic nanospheres in the reduction of Evans blue dye [J].
Jinendra, Usha ;
Bilehal, Dinesh ;
Nagabhushana, B. M. ;
Kumara, K. S. Jithendra ;
Kollur, Shiva Prasad .
HELIYON, 2021, 7 (01)
[23]   A simple and very sensitive spectrophotometric method for the direct determination of copper ions [J].
Juan, JP ;
Moreno, C ;
García-Vargas, M .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 373 (08) :844-848
[24]   Removal of heavy metals from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste [J].
Kadirvelu, K ;
Thamaraiselvi, K ;
Namasivayam, C .
BIORESOURCE TECHNOLOGY, 2001, 76 (01) :63-65
[25]   Activated carbon prepared from biomass as adsorbent: elimination of Ni(II) from aqueous solution [J].
Kadirvelu, K ;
Senthilkumar, P ;
Thamaraiselvi, K ;
Subburam, V .
BIORESOURCE TECHNOLOGY, 2002, 81 (01) :87-90
[26]   Removal of arsenic from an aqueous solution by coprecipitation with manganese oxide [J].
Kameda, Tomohito ;
Suzuki, Youhei ;
Yoshioka, Toshiaki .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2014, 2 (04) :2045-2049
[27]   Magnetic Fe3O4-graphene oxide/polystyrene: Fabrication and characterization of a promising nanocomposite [J].
Kassaee, M. Z. ;
Motamedi, E. ;
Majdi, M. .
CHEMICAL ENGINEERING JOURNAL, 2011, 172 (01) :540-549
[28]   Comparison of sorption and desorption studies of heavy metal ions from biochar and commercial active carbon [J].
Kolodynska, D. ;
Krukowska, J. ;
Thomas, P. .
CHEMICAL ENGINEERING JOURNAL, 2017, 307 :353-363
[29]   Application of magnetic particles modified with amino groups to adsorb copper ions in aqueous solution [J].
Lin, Yafen ;
Chen, Huawei ;
Lin, Kaelong ;
Chen, Boryann ;
Chiou, Chyowsan .
JOURNAL OF ENVIRONMENTAL SCIENCES, 2011, 23 (01) :44-50
[30]   Synthesis of porous Fe3O4 hollow microspheres/graphene oxide composite for Cr(VI) removal [J].
Liu, Mancheng ;
Wen, Tao ;
Wu, Xilin ;
Chen, Changlun ;
Hu, Jun ;
Li, Jie ;
Wang, Xiangke .
DALTON TRANSACTIONS, 2013, 42 (41) :14710-14717