Electroactive Carbazole-Based Polycyclic Aromatic Hydrocarbons: Synthesis, Photophysical Properties, and Computational Studies

被引：1

作者：

Wong, Hui Qi ^{[1
,2
,3
,4
]}

Lin, Ting-Hsuan ^{[1
,5
]}

Liao, Jian-Ming ^{[6
]}

Kholimatussadiah, Septia ^{[3
,7
]}

Baskoro, Febri ^{[1
]}

Tsai, Hui-Hsu Gavin ^{[6
,8
]}

Yen, Hung-Ju ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

[2] Acad Sinica, Sustainable Chem Sci & Technol Program, Taiwan Int Grad Program TIGP, Taipei 11529, Taiwan

[3] Natl Taiwan Univ, Taipei 11529, Taiwan

[4] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

[5] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 10607, Taiwan

[6] Natl Cent Univ, Dept Chem, Taoyuan City 32001, Taiwan

[7] Acad Sinica, Nano Sci & Technol Program, TIGP, Taipei 11529, Taiwan

[8] Natl Cent Univ, Res Ctr New Generat Light Driven Photovolta Modul, Taoyuan City 32001, Taiwan

来源：

ACS OMEGA | 2024年 / 9卷 / 27期

关键词：

ELECTROCHEMICAL SYNTHESIS; DEPOSITION;

D O I：

10.1021/acsomega.4c01434

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we explored the oxidative coupling reactions of carbazole-based polycyclic aromatic hydrocarbons using traditional Scholl reactions and electrochemical oxidation. Our findings indicate that the oxidation predominantly occurs at the carbazole functional group. The underlying reaction mechanisms were also clarified through theoretical investigations, highlighting that the primary oxidation pathway involves the 3,6-positions of the carbazole moiety, which is attributable to its high electron density.

引用

页码：29379 / 29390

页数：12

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