Two dinuclear Ln2 compounds: Synthesis, structures, magnetism and luminescence properties

被引：0

作者：

Guo, Yuyu ^{[1
]}

Zhang, Shen ^{[2
]}

机构：

[1] Taiyuan Univ Technol, Coll Arts, Jinzhong 030600, Shanxi, Peoples R China

[2] Taiyuan Normal Univ, Coll Chem & Mat, Jinzhong 030619, Shanxi, Peoples R China

来源：

POLYHEDRON | 2024年 / 255卷

关键词：

Dinuclear compounds; Quadrilateral dinuclear core; Magnetic properties; Magnetocaloric effect; SINGLE-MOLECULE MAGNET; REFRIGERATION; CLUSTERS; RELAXATION; GD; TEMPERATURE; NITROGEN; BEHAVIOR; ALLOYS; WHEEL;

D O I：

10.1016/j.poly.2024.116967

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isostructural lanthanide (Ln) compounds [Ln 2 L 4 (CH 3 COO) 2 (CH 3 OH) 2 ] (Ln = Gd ( 1) , Eu ( 2 ), L - =dibenzoylmethane) have been successfully synthesized and structurally characterized. The two compounds displayed a quadrilateral dinuclear core connected by two ketonic oxygens and each Ln ion was eightcoordinated with two bidentate L ligands, two acetoxy and one methoxy. Variable temperature magnetic susceptibility measurements revealed that a weak antiferromagnetic interaction was existed in compound 1 between Gd(III) ions and the maximum - Delta S m was 20.65 J kg - 1 K -1 for Delta H = 7 T at 2.0 K; while compound 2 only displayed luminescence properties.

引用

页数：5

共 50 条

[21] Structures and magnetic properties of acyloxy-O bridged Ln2 compounds: Gd2 compound displaying magnetic refrigeration property
Guan, Xiao-Fen
Shi, Peng-Fei
Xue, Miao-Miao
Fang, Zhi-Xuan
Yang, Li-Rong
Wang, Wen-Min
JOURNAL OF MOLECULAR STRUCTURE, 2021, 1233
[22] Structures, luminescence properties, magnetocaloric effect and slow magnetic relaxation of three Ln (III) complexes based on 8 hydroxyquinoline Schiff-base ligand
Wang, Wen-Min
Li, Hong-Hong
He, Liu-Ting
Han, Xue-Rong
Wu, Zhi-Lei
Ran, Yun-Gen
Zou, Ji-Yong
Fang, Ming
POLYHEDRON, 2017, 133 : 119 - 124
[23] Tetranuclear Ln2IIIMn2II cymantrenecarboxylates. Synthesis, structure, thermolysis and magnetic properties
Koroteev, Pavel S.
Efimov, Nikolay N.
Ilyukhin, Andrey B.
Dobrokhotova, Zhanna V.
Novotortsev, Vladimir M.
INORGANICA CHIMICA ACTA, 2014, 418 : 157 - 162
[24] Four Ln2 compounds constructed by a polydentate Schiff base ligand: Gd2 compound displaying large magnetocaloric effect and Dy2 compound showing single-molecule magnet behavior
Wang, Qin
Gao, Hui-Min
Xue, Wen-Juan
Chen, Kai-Yang
Zhang, Quan
Huang, Min
Wang, Rui-Feng
Fan, Wen-Liang
Hua, Yu-Peng
Fang, Ming
POLYHEDRON, 2022, 212
[25] Syntheses, structures and magnetic properties of symmetrical Schiff-base supported dinuclear Ln(III) compounds
Lin, Shuang-Yan
Wang, Chunlai
Xu, Zhikun
RSC ADVANCES, 2016, 6 (105): : 103035 - 103041
[26] Structural Characterization and Luminescence Properties of Two 4d-4f Ln-Ag Coordination Compounds Based on Dinuclear Lanthanide Clusters
Zhang Yu
Chen Lei
Ju Weiwei
Xu Yan
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2014, 30 (02) : 194 - 199
[27] Two Oxime-Based {Ln3IIINi3II} Clusters with Triangular {Ln3(μ3-O2)}7+ Core: Solvothermal Syntheses, Crystal Structures, and Magnetic Properties
Wang, Xiao-Ting
Dong, Hui-Ming
Wang, Xiu-Guang
Yang, En-Cui
Zhao, Xiao-Jun
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (20): : 1166 - 1172
[28] Synthesis, structure and luminescence properties of a series of dinuclear LnIII complexes (Ln=Gd, Tb, Dy, Ho, Er)
Zhang, Li
Ji, Yufei
Xu, Xuebin
Liu, Zhiliang
Tang, Jinkui
JOURNAL OF LUMINESCENCE, 2012, 132 (08) : 1906 - 1909
[29] Crystal structure, fluorescence properties and biological activity of three μ2-O bridged Ln2 (Ln = Sm, Eu and Tb) compounds
Xin, Xiao-Yan
Qiao, Na
Cao, Chun-Shuai
Chen, Feng-Jiao
Li, Wen-Yu
Ling, Yan-Ni
Shi, Xiao-Hong
Shi, Ying
Li, Min
Wu, Zhi-Lei
Wang, Wen-Min
INORGANICA CHIMICA ACTA, 2022, 541
[30] Syntheses, crystal structures, and magnetic properties of a series of Fe2Ln complexes
Kuang, Wei-Wei
Shao, Cong-Ying
Yang, Pei-Pei
JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (08) : 1412 - 1422

← 1 2 3 4 5 →