Poly3-Hexylthiophene Titanium Dioxide (P3HT-TiO2) Composite Sensor for High Response Detection of Ammonia at Room Temperature

被引:1
作者
Fei, Yuqian [1 ]
Nie, Zizhuo [1 ]
Ding, Shujiang [1 ]
Wang, Jiuhong [2 ]
Yu, Wei [1 ]
Li, Na [1 ]
Liu, Yuhang [3 ]
Peng, Bo [3 ]
Feng, Xiaoli [4 ]
Liu, Limin [1 ]
Jiang, Xinbing [1 ]
机构
[1] Xi An Jiao Tong Univ, Engn Res Ctr Energy Storage Mat & Devices, Sch Chem, Minist Educ, Xian 710049, Peoples R China
[2] Xi An Jiao Tong Univ, Sch Instrument Sci & Technol, Xian 710049, Peoples R China
[3] Beijing Machine & Equipment Inst, 50 Yong Ding Rd, Beijing 100854, Peoples R China
[4] Yanan Inst Qual & Technol Testing 3, Yanhe East Rd, Yanan 716000, Peoples R China
来源
CHEMNANOMAT | 2024年 / 10卷 / 07期
基金
中国国家自然科学基金; 国家重点研发计划; 中国博士后科学基金;
关键词
Conductive polymer; NH3 gas sensing; P3HT; Room temperature sensing; TiO2; nanoparticles; GAS-SENSING PROPERTIES; NH3; PERFORMANCE; NANOCOMPOSITE; POLY(3-HEXYLTHIOPHENE); SENSITIVITY; OXIDE; PRISTINE; FILM; TI;
D O I
10.1002/cnma.202400053
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gas sensors for ammonia (NH3) play a crucial role in the maintenance of air quality, preservation of the atmosphere, and evaluation of human health. However, the endeavor to attain a high level of sensitivity in detecting NH3 under ambient conditions remains a challenging task. In this work, poly(3-hexylthiophene)s and titanium dioxide (P3HT-TiO2) heterostructure NH3 gas-sensitive material was prepared, and by drop-casting the material onto a substrate with Au interdigital electrodes, a sensor for high-response detection of NH3 at room temperature was constructed. The designed gas sensor exhibited a high response signal of 114.61 % toward 15 ppm NH3 at room temperature (25 degrees C) with good reproducibility, strong long-term stability, and excellent selectivity. Moreover, by analyzing the response law of the sensor under different humidity conditions, it has been noted that both excessively high and excessively low levels of humidity adversely affect the sensor's response. The remarkable increase in NH3 sensing properties is attributed to the synergistic enhancement effect of P-N heterojunction formed between P3HT and TiO2. This NH3 gas sensor exhibits tremendous potential for use due to its straightforward structure and outstanding ammonia sensing performance.
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页数:10
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