Improved electrocatalytic activity of selenide nanoparticle for oxygen evolution reaction

被引:3
|
作者
Somaily, H. H. [1 ]
机构
[1] King Khalid Univ, Fac Sci, Dept Phys, POB 9004, Abha, Saudi Arabia
关键词
NbSe2/g-CN; Oxygen evolution reaction; Electrocatalyst; Hydrothermal method; Alkaline medium; TRANSITION-METAL DICHALCOGENIDE; GRAPHITIC CARBON; EFFICIENT; ELECTRODE; OER;
D O I
10.1016/j.jallcom.2024.174797
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Oxygen Evolution Reaction (OER) plays a vital role in water electrolysis, but its slow kinetics and expensive catalysts are obstacles to widespread use. To improve the OER activity, it is crucial to create a well-structured design for electrocatalysts based on transition metals, which may be applied to a conducting polymer substrate. This research reports a facile hydrothermal synthesis and remarkable catalytic behavior of NbSe2/g-CN as an OER catalyst in an alkaline condition. The fabricated electrocatalysts were examined utilizing numerous analytical techniques to assess their crystallinity, oxidation states and morphology. NbSe2/g-CN shows enhanced electro-catalytic behavior to OER in alkaline solution (1.0 KOH) with minor overpotential (196 mV) and Tafel slop (38 mV/dec) than pristine NbSe2 electrocatalyst was associated with the exceptional conductivity of NF and its highly porous structure, along with a greater SSA. In addition, the durability of the electrocatalyst was examined via cyclic stability and chronoamperometry study over 40 h. This study demonstrates that TMSe with specific morphology can improve electrocatalytic activity when combined with g-CN, demonstrating its potential for reliable and eco-friendly energy generation
引用
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页数:10
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