Magnetic-dipole transitions in free lanthanide (3+) ions Ln IV

被引:0
|
作者
Petrov, Dimitar N. [1 ]
Angelov, B. M. [2 ]
机构
[1] Plovdiv Univ Paisii Hilendarski, Dept Phys Chem, 24 Tsar Asen Str, Plovdiv 4000, Bulgaria
[2] Univ Food Technol, Dept Inorgan & Phys Chem, 26 Maritsa Boul, Plovdiv 4000, Bulgaria
关键词
Free lanthanide (3+) ions; Magnetic -dipole transitions; TM IV; EMISSION; SPECTRUM;
D O I
10.1016/j.physb.2024.416135
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Oscillator strengths have been evaluated for magnetic-dipole transitions in free lanthanide (3+) ions: Ce IV, Pr IV, Nd IV, Er IV, Tm IV, and Yb IV, within ground-state 4fN configurations. The calculations are based on known experimental 4f-electronic energy levels in these ions. The wave functions used are in LS-coupling scheme or in intermediate coupling approximation (Pr IV, Er IV, Tm IV). The obtained values have been compared with other theoretical and experimental results. It has been found that about 2/3 of the values of the magnetic moments in these optical transitions correspond to the ground-state effective magnetic moments in the free ions Ln IV.
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页数:4
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