Continuous flow ring-opening polymerization and ring-opening metathesis polymerization

被引：5

作者：

Liu, Yihuan ^{[1
]}

Ou, Shi ^{[1
]}

Wu, Jiaqi ^{[1
]}

Zhao, Rongji ^{[1
]}

Hou, Ruixiang ^{[2
]}

Li, Xiaomin ^{[2
]}

Sun, Yongxiang ^{[3
]}

Li, Yuguang ^{[4
]}

Hu, Xin ^{[5
]}

Zhu, Ning ^{[1
]}

Guo, Kai ^{[1
,6
]}

机构：

[1] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, Nanjing 211816, Peoples R China

[2] Sinopec, Beijing Res Inst Chem Ind, Beijing 100013, Peoples R China

[3] Sumec Text Technol & Ind Co LTD, Nanjing 210019, Peoples R China

[4] Inst Nanjing Adv Biomat & Proc Equipment, Nanjing 211299, Peoples R China

[5] Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 211816, Peoples R China

[6] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2024年 / 216卷

关键词：

Continuous flow; Ring-opening polymerization; Ring-opening metathesis polymerization; Polymer synthesis; MICROWAVE-ASSISTED POLYMERIZATIONS; OLEFIN METATHESIS; ENZYMATIC-SYNTHESIS; SYNTHETIC APPROACH; CARBON-DIOXIDE; SCALE-UP; CATALYSTS; POLY(EPSILON-CAPROLACTONE); 2-ETHYL-2-OXAZOLINE; BOTTLEBRUSH;

D O I：

10.1016/j.eurpolymj.2024.113288

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The combination of microflow technology and ring-opening polymerization (ROP) or ring-opening metathesis polymerization (ROMP) has been proved to be an effective method for well-defined polymers. Microreactorbased ROP or ROMP enables the distinguished advantages over traditional batchwise reactor, including faster apparent polymerization rate, higher conversion and chemoselectivity, narrower dispersity, easier scale-up and the ability to telescope several synthetic steps into a single system. In this view, ROP of a variety of cyclic monomers was highlighted, including lactone, lactide, epoxide, 2-oxazoline, N-carboxyanhydride and cyclic phosphoester. ROMP in the context of flow chemistry was introduced. Challenges and opportunities are proposed for the future development of continuous flow ROP and ROMP.

引用

页数：17

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