Electrochemical evaluation of low crystalline CoFe2O4@Reduced graphene oxide nanocomposite for hybrid supercapacitor application

被引:3
作者
Lishavi, S. Pandimadevi [1 ]
Ansari, M. Thameem [1 ]
Raja, K. Karthick [2 ]
Kumar, Vivek [2 ]
机构
[1] Manonmaniam Sundaranar Univ, Sadakathullah Appa Coll Autonomous, Dept Chem, Tirunelveli 627012, Tamil Nadu, India
[2] Indian Inst Informat Technol Design & Mfg Kancheep, Dept Phys, Appl Nanomat & Devices Lab, Chennai 600127, India
关键词
Binary transition metal oxide; Low crystalline; Reduced graphene oxide; Supercapacitor; NANOPARTICLES;
D O I
10.1016/j.chemphys.2024.112372
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of high-performance and cost-effective energy storage materials remains of significant scientific interest. Here, low-crystalline (LC) binary transition metal oxide (BTMO) CoFe2O4 is studied for its application in a hybrid supercapacitor. This disordered LC CoFe2O4 material was prepared by the co-precipitation method, and to improve the electron transport property of the LC CoFe2O4, a composite was prepared with reduced graphene oxide (RGO). LC CoFe2O4@rGO interconnected network enhances the electrolyte ion diffusion within the material. This CoFe2O4@RGO shows an electrochemical performance of 2247.82 mF cm-2 at a current density of 1 mA cm-2. The cyclic stability study is performed to CF@RGO 20 % electrode for 2000 cycles at 30 mA cm-2 current density. Further, to understand the charge storage mechanism, Dunn analysis is done, the capacitive and diffusion contributions to charge storage are studied. Besides, the charge transfer and diffusion characteristics of the material were studied using electrochemical impedance spectroscopy. So, these LC CoFe2O4@RGO based materials with improved ion diffusivity and flexibility in synthesis make them attractive candidates for the development of high-performance and cost-effective supercapacitor.
引用
收藏
页数:10
相关论文
共 36 条
  • [1] Enhanced electrochemical performance of MnNi2O4/rGO nanocomposite as pseudocapacitor electrode material and methanol electro-oxidation catalyst
    Askari, Mohammad Bagher
    Salarizadeh, Parisa
    Di Bartolomeo, Antonio
    Sen, Fatih
    [J]. NANOTECHNOLOGY, 2021, 32 (32)
  • [2] ZnFe2O4 nanorods on reduced graphene oxide as advanced supercapacitor electrodes
    Askari, Mohammad Bagher
    Salarizadeh, Parisa
    Seifi, Majid
    Zadeh, Mohammad Hassan Ramezan
    Di Bartolomeo, Antonio
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 860
  • [3] Binary nickel ferrite oxide (NiFe2O4) nanoparticles coated on reduced graphene oxide as stable and high-performance asymmetric supercapacitor electrode material
    Askari, Mohammad Bagher
    Salarizadeh, Parisa
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (51) : 27482 - 27491
  • [4] Comprehensive Insight into the Mechanism, Material Selection and Performance Evaluation of Supercapatteries
    Balasubramaniam, Saravanakumar
    Mohanty, Ankita
    Balasingam, Suresh Kannan
    Kim, Sang Jae
    Ramadoss, Ananthakumar
    [J]. NANO-MICRO LETTERS, 2020, 12 (01)
  • [5] Calcination effect on structural, morphological and magnetic properties of nano-sized CoFe2O4 developed by a simple co-precipitation technique
    Basak, Munmun
    Rahman, Md. Lutfor
    Ahmed, Md. Farid
    Biswas, Bristy
    Sharmin, Nahid
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2021, 264
  • [6] Conway B. E, 2013, Electrochemical supercapacitors: scientific fundamentals and technological applications
  • [7] Clipping electron transport and polarization relaxation of Ti3C2Tx based nanocomposites towards multifunction
    Fang, Yong-Sheng
    Yuan, Jie
    Liu, Ting -Ting
    Wang, Qiang-Qiang
    Cao, Wen-Qiang
    Cao, Mao-Sheng
    [J]. CARBON, 2023, 201 : 371 - 380
  • [8] CoFe2O4 Hollow Spheres-Decorated Three-Dimensional rGO Sponge for Highly Efficient Electrochemical Charge Storage Devices
    Gogoi, Debika
    Das, Manash R.
    Ghosh, Narendra Nath
    [J]. ACS OMEGA, 2022, 7 (13): : 11305 - 11319
  • [9] The supercapacitor electrode properties and energy storage mechanism of binary transition metal sulfide MnCo2S4 compared with oxide MnCo2O4 studied using in situ quick X-ray absorption spectroscopy
    Hsu, Su-Yang
    Hsu, Feng-Hao
    Chen, Jeng-Lung
    Cheng, Yu-Song
    Chen, Jin-Ming
    Lu, Kueih-Tzu
    [J]. MATERIALS CHEMISTRY FRONTIERS, 2021, 5 (13) : 4937 - 4949
  • [10] Contribution of electron localization and delocalization zones in the performance of electrochemically reduced graphene oxide based supercapacitors: An experimental and the first-principles study
    Karthick, Raja K.
    Anusuya, T.
    Kumar, Vivek
    [J]. CARBON, 2023, 215