Synthesis, structural, and optical properties of MnO2/AC/r-GO nanocomposites for highly efficient under visible light photocatalytic activity

被引:1
|
作者
Manikandan, S. [1 ]
Sasikumar, D. [2 ]
机构
[1] Muthayammal Coll Arts & Sci Autonomous, Dept Phys, Namakkal 637408, Tamil Nadu, India
[2] Arignar Anna Govt Arts Coll, PG & Res Dept Phys, Namakkal 637002, Tamil Nadu, India
关键词
MnO2/AC/r-GO NCs; Graphite powder; Onion peel; Organic dye; Photocatalysis; FACILE SYNTHESIS; DEGRADATION; NANOSHEET; COMPOSITE; G-C3N4;
D O I
10.1007/s11581-024-05735-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Significant increases in photocatalytic degradation performance have been partially attributed to the contributions of AC, r-GO, MnO2, and their composite species. Activated carbon, r-GO, and MnO2 are dispersed and in good touch with one another. The current study describes the hydrothermal synthesis of nanorod-shaped MnO2 nanostructures and MnO2/AC, MnO2/r-GO, and MnO2/AC/r-GO (MAG NCs) NCs. Various analytical methods were used to examine the structural, bonding, morphological, and photocatalytic aspects of the material. Morphological characterizations (SEM, FE-SEM, and TEM) demonstrated that activated carbon and r-GO coated the MnO2 nanorods. The MAG surface area was studied using BET analysis. Remarkably, MAG NCs have a surface area of 68.8 m(2)g(-1). According to the UV-Vis DRS findings, the optical absorption of MAG NCs was blue-shifted into the visible range. Furthermore, photocatalytic elimination of MO dye in aqueous solution employing the resultant catalysts reaches a maximum degradation efficiency of 97.36% under visible light irradiation for 60 min as compared to MnO2/AC (83.11%), MnO2/r-GO (81.81%), and MnO2 (64.17%). The blue-shifted band gap was attributable to the increase in photocatalytic degradation efficiency of MAG NCs (2.148 eV). Furthermore, the MAG ternary NCs had remarkable chemical stability and had a wide range of applications in photocatalytic dye degradation and wastewater treatment.
引用
收藏
页码:6591 / 6610
页数:20
相关论文
共 50 条
  • [31] Photocatalytic activity of polypyrrole/TiO2 nanocomposites under visible and UV light
    Qingzhi Luo
    Xueyan Li
    Desong Wang
    Yanhong Wang
    Jing An
    Journal of Materials Science, 2011, 46 : 1646 - 1654
  • [32] Photocatalytic activity of polypyrrole/TiO2 nanocomposites under visible and UV light
    Luo, Qingzhi
    Li, Xueyan
    Wang, Desong
    Wang, Yanhong
    An, Jing
    JOURNAL OF MATERIALS SCIENCE, 2011, 46 (06) : 1646 - 1654
  • [33] Direct Z-Scheme AgBr/β-MnO2 Photocatalysts for Highly Efficient Photocatalytic and Anticancer Activity
    Warshagha, Murad Z. A.
    Muneer, Mohammad
    ACS OMEGA, 2022, 7 (34): : 30171 - 30183
  • [34] Synthesis, structural, dielectric and magnetic properties of CuFe2O4/MnO2 nanocomposites
    Ali, Kashif
    Bahadur, Ali
    Jabbar, Abdul
    Iqbal, Shahid
    Ahmad, Ijaz
    Bashir, Muhammad Imran
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2017, 434 : 30 - 36
  • [35] The enhanced photocatalytic properties of MnO2/g-C3N4 heterostructure for rapid sterilization under visible light
    Wu, Beibei
    Li, Yuan
    Su, Kun
    Tan, Lei
    Liu, Xiangmei
    Cui, Zhenduo
    Yang, Xianjin
    Liang, Yanqin
    Li, Zhaoyang
    Zhu, Shengli
    Yeung, Kelvin Wai Kwok
    Wu, Shuilin
    JOURNAL OF HAZARDOUS MATERIALS, 2019, 377 : 227 - 236
  • [36] Phthaloyanine-sensitized CNS nanocomposites with efficient photocatalytic activity under visible-light irradiation
    Zhang, Miao
    Liang, Qian
    Xu, Song
    Li, Zhongyu
    OPTIK, 2016, 127 (19): : 7993 - 8001
  • [37] Highly efficient photocatalytic hydrogen evolution of graphene/YInO3 nanocomposites under visible light irradiation
    Ding, Jianjun
    Yan, Wenhao
    Xie, Wei
    Sun, Song
    Bao, Jun
    Gao, Chen
    NANOSCALE, 2014, 6 (04) : 2299 - 2306
  • [38] Structural and photocatalytic properties of GO/ErBO3 for dye degradation under visible light irradiation
    Zhao, Wenwu
    Zhang, Mingming
    Li, Zihan
    Li, Shizhuo
    Zhang, Jiaqi
    Liu, Jian
    Hao, Bin
    Zhao, Lihong
    Liu, Xiaowen
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (15)
  • [39] Highly efficient photocatalytic bismuth oxide coatings and their antimicrobial properties under visible light irradiation
    Ratova, Marina
    Redfern, James
    Verran, Joanna
    Kelly, Peter J.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 239 : 223 - 232
  • [40] Visible light induced photocatalytic activity of MnO2/BiVO4 for the degradation of organic dye and tetracycline
    Liaqat, Maira
    Khalid, N. R.
    Tahir, M. B.
    Znaidia, Sami
    Alrobei, Hussein
    Alzaid, Meshal
    CERAMICS INTERNATIONAL, 2023, 49 (07) : 10455 - 10461