Synthesis, structural, and optical properties of MnO2/AC/r-GO nanocomposites for highly efficient under visible light photocatalytic activity

被引:1
|
作者
Manikandan, S. [1 ]
Sasikumar, D. [2 ]
机构
[1] Muthayammal Coll Arts & Sci Autonomous, Dept Phys, Namakkal 637408, Tamil Nadu, India
[2] Arignar Anna Govt Arts Coll, PG & Res Dept Phys, Namakkal 637002, Tamil Nadu, India
关键词
MnO2/AC/r-GO NCs; Graphite powder; Onion peel; Organic dye; Photocatalysis; FACILE SYNTHESIS; DEGRADATION; NANOSHEET; COMPOSITE; G-C3N4;
D O I
10.1007/s11581-024-05735-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Significant increases in photocatalytic degradation performance have been partially attributed to the contributions of AC, r-GO, MnO2, and their composite species. Activated carbon, r-GO, and MnO2 are dispersed and in good touch with one another. The current study describes the hydrothermal synthesis of nanorod-shaped MnO2 nanostructures and MnO2/AC, MnO2/r-GO, and MnO2/AC/r-GO (MAG NCs) NCs. Various analytical methods were used to examine the structural, bonding, morphological, and photocatalytic aspects of the material. Morphological characterizations (SEM, FE-SEM, and TEM) demonstrated that activated carbon and r-GO coated the MnO2 nanorods. The MAG surface area was studied using BET analysis. Remarkably, MAG NCs have a surface area of 68.8 m(2)g(-1). According to the UV-Vis DRS findings, the optical absorption of MAG NCs was blue-shifted into the visible range. Furthermore, photocatalytic elimination of MO dye in aqueous solution employing the resultant catalysts reaches a maximum degradation efficiency of 97.36% under visible light irradiation for 60 min as compared to MnO2/AC (83.11%), MnO2/r-GO (81.81%), and MnO2 (64.17%). The blue-shifted band gap was attributable to the increase in photocatalytic degradation efficiency of MAG NCs (2.148 eV). Furthermore, the MAG ternary NCs had remarkable chemical stability and had a wide range of applications in photocatalytic dye degradation and wastewater treatment.
引用
收藏
页码:6591 / 6610
页数:20
相关论文
共 50 条
  • [1] Enhancing photocatalytic activity through 2D heterostructured P/MnO2/r-GO nanocomposites: a study on synthesis, structure, and optical properties
    Manikandan, S.
    Sasikumar, D.
    Dhinesh, S.
    Seenivasan, S.
    Manonmani, R.
    Vijayakumar, P.
    IONICS, 2023, 29 (10) : 4295 - 4310
  • [2] Enhancing photocatalytic activity through 2D heterostructured P/MnO2/r-GO nanocomposites: a study on synthesis, structure, and optical properties
    S. Manikandan
    D. Sasikumar
    S. Dhinesh
    S. Seenivasan
    R. Manonmani
    P. Vijayakumar
    Ionics, 2023, 29 : 4295 - 4310
  • [3] Highly efficient visible light driven photocatalytic activity of MnO2 and Polythiophene/MnO2 nanohybrids against mixed organic pollutants
    Zia, Jannatun
    Aazam, Elham S.
    Riaz, Ufana
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1207
  • [4] Electrodeposition synthesis of MnO2/TiO2 nanotube arrays nanocomposites and their visible light photocatalytic activity
    Xu, Xuyao
    Zhou, Xiaosong
    Li, Xiaoyu
    Yang, Fei
    Jin, Bei
    Xu, Tan
    Li, Guosheng
    Li, Manyi
    MATERIALS RESEARCH BULLETIN, 2014, 59 : 32 - 36
  • [5] Synthesis and photocatalytic activity of highly efficient NiFe2O4/r-GO based photocatalyst
    Joshi, Naveen Chandra
    Upadhyay, Sanjay
    Kumar, Niraj
    Chatana, S.
    Juyal, Ashima
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2024, 45 (04) : 768 - 779
  • [6] Europium-doped MnO2 nanostructures for controlling optical properties and visible light photocatalytic activity
    Panimalar, S.
    Chandrasekar, M.
    Logambal, S.
    Uthrakumar, R.
    Inmozhi, C.
    MATERIALS TODAY-PROCEEDINGS, 2022, 56 : 3394 - 3401
  • [7] Facile Synthesis of r-GO@Pd/TiO2 Nanocomposites and Its Photocatalytic Activity Under Visible Light
    Anh Quang Dao
    Zheng, Bijuan
    Liu, Hongwei
    Dong, Shuang
    Thanh Tuyen Le Thi
    Fu, Chaoyang
    Liu, Hongfang
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (04) : 3557 - 3563
  • [8] Synthesis of ZnO/titanate nanocomposites with highly photocatalytic activity under visible light irradiation
    Liu, Gang
    Li, Guangshe
    Qiu, Xiaoqing
    Li, Liping
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) : 492 - 497
  • [9] Photocatalytic activity of β-MnO2 nanotubes grown on PET fibre under visible light irradiation
    Chan, Yim-Leng
    Pung, Swee-Yong
    Sreekantan, Srimala
    Yeoh, Fei-Yee
    JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2016, 11 (08) : 603 - 618
  • [10] Synthesis of ε-MnO2 in deep eutectic solvent for visible-light-driven photocatalytic activity
    Lai X.
    Cheng Y.
    Han C.
    Luo G.
    Materials Research Innovations, 2019, 23 (05): : 305 - 309