Non-isothermal Kinetic Analysis of High Temperature Oxidation of Additively Manufactured Ti-6Al-4V Alloy

被引:1
作者
Demirci, Selim [1 ]
Yildirim, Bercem Kiran [2 ]
Tuncay, Mehmet Masum [1 ]
Kaya, Nusret [3 ]
Dikici, Tuncay [4 ]
机构
[1] Marmara Univ, Fac Engn, Dept Met & Mat Engn, TR-34854 Istanbul, Turkiye
[2] Marmara Univ, Fac Engn, Dept Chem Engn, TR-34854 Istanbul, Turkiye
[3] Katip Celebi Univ, Cent Res Labs Applicat & Res Ctr, TR-35620 Izmir, Turkiye
[4] Dokuz Eylul Univ, Torbali Vocat Sch, Welding Technol Dept, TR-35860 Izmir, Turkiye
关键词
Ti-6Al-4V; additive manufacturing; heating rate; kinetic analysis; thermal oxidation; CRYSTALLIZATION PROCESS; THERMAL-OXIDATION; ACTIVATION-ENERGY; TITANIUM-ALLOYS; BEHAVIOR; MICROSTRUCTURE; PYROLYSIS; TI6AL4V; SURFACE; PARAMETERS;
D O I
10.1007/s11665-024-09557-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, for the first time, non-isothermal oxidation behavior of the AM Ti-6Al-4V alloy was investigated through TGA-DTA to predict and determine the oxidation mechanism. TGA results were evaluated by both model-free kinetic models and model-fitting methods. The model-fitting kinetic method was applied to predict and determine the reaction mechanism. The obtained results indicate that the reaction is controlled by D2 and D3 models at heating rates of 5 and 10 degrees C/min, respectively. F2 and F1 control the reaction mechanism at heating rates of 20 and 50 degrees C/min, respectively. The results of this study indicate that oxidation kinetics vary with reaction time, allowing us to predict which materials are most favorable to use under certain conditions with respect to oxidation applications.
引用
收藏
页码:5773 / 5784
页数:12
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