Facile synthesis of Zn 2 V 2 O 7 /RGO nanocomposite for enhancing the electrochemical performance and evaluating the supercapacitor device

被引:7
作者
Murugesan, M. [1 ]
Nagavenkatesh, K. R. [1 ]
Devendran, P. [1 ]
Nallamuthu, N. [2 ]
Uthayakumar, T. [3 ]
机构
[1] Kalasalingam Acad Res & Educ, Int Res Ctr, Sch Adv Sci, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[2] Dayananda Sagar Acad Technol & Management, Dept Phys, Bangalore 560082, Karnataka, India
[3] Dayananda Sagar Coll Engn, Dept Phys, Shavige Malleshwara Hills, Bangalore 560111, Karnataka, India
关键词
Hydrothermal technique; Pyrochlore structured; Electrochemical; Supercapacitors; Energy storage; ELECTRODE MATERIALS; ANODE MATERIAL; NANORODS; NANOSTRUCTURES; ZN2V2O7; STORAGE; NANOPARTICLES; MECHANISMS; NANOWIRES;
D O I
10.1016/j.inoche.2024.112544
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Pyrochlore-structured zinc vanadium oxide with RGO (Zn 2 V 2 O 7 /RGO) composite was synthesized using the simple hydrothermal process for energy storage device fabrication. The structural, vibration spectrum, surface morphology, and elemental of the Zn 2 V 2 O 7 /RGO composite were analyzed using different analytical methods. Then, the electrochemical performance was examined using Zn 2 V 2 O 7 /RGO composite modified electrode with 3electrode and 2 -electrode setup by cyclic voltammetry (CV), galvanostatic charge - discharge (GCD), and electrochemical impedance spectrum (EIS) techniques. Consequently, the Zn 2 V 2 O 7 /RGO composite revealed notable pseudo -capacitive behavior which has been confirmed through CV analysis. The nano size -based Zn 2 V 2 O 7 /RGO composite electrode material obtained notable specific capacitance (Csp) of 1400.51F/g owing to the synergistic promotion of Zinc and vanadium oxides. Furthermore, the ASC device of Zn 2 V 2 O 7 /RGO ||RGO displayed the efficient power density of 1371 kW/kg at the energy density of 8Wh/kg and the device has enhanced cycling performance with 72.8 % capacitance.
引用
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页数:14
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