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Facile synthesis of Zn 2 V 2 O 7 /RGO nanocomposite for enhancing the electrochemical performance and evaluating the supercapacitor device
被引:7
|作者:
Murugesan, M.
[1
]
Nagavenkatesh, K. R.
[1
]
Devendran, P.
[1
]
Nallamuthu, N.
[2
]
Uthayakumar, T.
[3
]
机构:
[1] Kalasalingam Acad Res & Educ, Int Res Ctr, Sch Adv Sci, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[2] Dayananda Sagar Acad Technol & Management, Dept Phys, Bangalore 560082, Karnataka, India
[3] Dayananda Sagar Coll Engn, Dept Phys, Shavige Malleshwara Hills, Bangalore 560111, Karnataka, India
关键词:
Hydrothermal technique;
Pyrochlore structured;
Electrochemical;
Supercapacitors;
Energy storage;
ELECTRODE MATERIALS;
ANODE MATERIAL;
NANORODS;
NANOSTRUCTURES;
ZN2V2O7;
STORAGE;
NANOPARTICLES;
MECHANISMS;
NANOWIRES;
D O I:
10.1016/j.inoche.2024.112544
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Pyrochlore-structured zinc vanadium oxide with RGO (Zn 2 V 2 O 7 /RGO) composite was synthesized using the simple hydrothermal process for energy storage device fabrication. The structural, vibration spectrum, surface morphology, and elemental of the Zn 2 V 2 O 7 /RGO composite were analyzed using different analytical methods. Then, the electrochemical performance was examined using Zn 2 V 2 O 7 /RGO composite modified electrode with 3electrode and 2 -electrode setup by cyclic voltammetry (CV), galvanostatic charge - discharge (GCD), and electrochemical impedance spectrum (EIS) techniques. Consequently, the Zn 2 V 2 O 7 /RGO composite revealed notable pseudo -capacitive behavior which has been confirmed through CV analysis. The nano size -based Zn 2 V 2 O 7 /RGO composite electrode material obtained notable specific capacitance (Csp) of 1400.51F/g owing to the synergistic promotion of Zinc and vanadium oxides. Furthermore, the ASC device of Zn 2 V 2 O 7 /RGO ||RGO displayed the efficient power density of 1371 kW/kg at the energy density of 8Wh/kg and the device has enhanced cycling performance with 72.8 % capacitance.
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页数:14
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