Covalent Organic Frameworks for Electrocatalysis: Design, Applications, and Perspectives

Covalent organic frameworks (COFs) are an innovative class of crystalline porous polymers composed of light elements such as C, N, O, etc., linked by covalent bonds. The distinctive properties of COFs, including designable building blocks, large specific surface area, tunable pore size, abundant active sites, and remarkable stability, have led their widespread applications in electrocatalysis. In recent years, COF-based electrocatalysts have made remarkable progress in various electrocatalytic fields, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, nitrogen reduction reaction, nitrate reduction reaction, and carbon dioxide reduction reaction. This review begins with an introduction to the design and synthesis strategies employed for COF-based electrocatalysts. These strategies include heteroatom doping, metalation of COF and building monomers, encapsulation of active sites within COF pores, and the development of COF-based derived materials. Subsequently, a systematic overview of the recent advancements in the application of COF-based catalysts in electrocatalysis is presented. Finally, the review discusses the main challenges and outlines possible avenues for the future development of COF-based electrocatalysts. Covalent organic frameworks (COFs) are a category of crystalline porous polymers widely used in the field of electrocatalysis. Their designable structure, substantial specific surface area, abundant active sites and remarkable stability contribute to their widespread application. This review provides a comprehensive overview of the strategies underlying COF-based electrocatalysts, examines their recent applications, and outlines future prospects in this burgeoning field. image