Preparation of a Cu-Doped Graphene Oxide-Glutamine Nanocomposite for Supercapacitor Electrode Applications: An Experimental and Theoretical Study

被引:6
作者
Mohammadi, Samira [1 ]
Mousavi-Khoshdel, Seyed Morteza [1 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Ind Electrochem Res Lab, Tehran 1684613114, Iran
关键词
glutamine; graphene oxide; quantumcapacitance; restacking; supercapacitor; QUANTUM CAPACITANCE; PERFORMANCE; COPPER; CARBON; NANOPARTICLES; FABRICATION; GROWTH; MOS2;
D O I
10.1021/acsaelm.4c00224
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this study, using graphene oxide (GO), glutamine (G), and Cu(II) nanoparticles, a nanocomposite was prepared. Then, the prepared nanocomposite was checked out by various techniques such as X-ray diffraction, Fourier transform infrared, Raman spectrum, scanning electron microscopy, and energy-dispersive X-ray, and the results showed that the desired structure was successfully prepared. Also, a three-electrode system was utilized to measure the electrochemical properties. The specific capacitance of a Cu-doped graphene oxide-glutamine nanocomposite (Cu/G-GO) of 1838 F g-1 was obtained in a 1 M H2SO4 aqueous electrolyte under a current density of 3 A g-1. Moreover, 85.43% of the initial capacitance of the electrode was preserved after 5000 cycles at 20 A g-1 (10,000 cycles, 73.12%). Also, the quantum capacitance and the layer distance of GO and G-GO using density functional theory were calculated.
引用
收藏
页码:4108 / 4119
页数:12
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