Super-Stable Mineralization of Metal Ions from Smelting Wastewater by In Situ Synthesis of NiFe-Based Layered Double Hydroxides for Catalytic Phenol Hydroxylation

The super-stable mineralization of metal ions from industrial wastewater by in situ synthesis of layered double hydroxides (LDHs) has been regarded as a sustainable approach from environmental protection and resource utilization perspectives. Herein, the study reports a super-stable mineralization of metal ions including Ni, Fe, Cr, Mn, Cu, Ca, Al, etc. from smelting wastewater by in situ synthesis of NiFe-based LDHs through facile coprecipitation. Such approach exhibits superior mineralization efficiency of metal ions simultaneously that can remove hundreds, thousands, or even tens of thousands mg/L of multiple metal ions to below the values of the Chinese National Emission Standards of Pollutants. Furthermore, the obtained NiFe-based LDHs exhibit excellent catalytic performance of phenol hydroxylation due to the mineralization of multiple metals on the laminates, where 48.24% conversion of phenol and 71.58% selectivity of dihydroxybenzenes are realized under room temperature for 3 h. This work paves a sustainable strategy for hazardous material disposal and resource utilization. Simultaneous mineralization of multiple metal ions from smelting wastewater is achieved by in situ synthesis of NiFe-based layered double hydroxides (NiFe-based LDHs). The obtained NiFe-based LDHs laminates consisting of multiple metals contained Fe, Ni, Cu, and other valence metals are beneficial for catalytic phenol hydroxylation based on the Fenton reaction. image