Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes

被引：10
作者：
Fomenko, Iakov S. [1 ]
Romashev, Nikolay F. [1 ]
Gushchin, Artem L. [1 ]
机构：
[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Lavrentiev Ave, Novosibirsk 630090, Russia
来源：
COORDINATION CHEMISTRY REVIEWS | 2024年 / 514卷
基金：
俄罗斯科学基金会;
关键词：
Bis(imino)acenaphthenes; Redox active ligands; Transition metals; ALPHA-DIIMINE NICKEL; BIDENTATE NITROGEN LIGANDS; CHAIN-WALKING POLYMERIZATION; AGGREGATION-INDUCED EMISSION; RAY CRYSTAL-STRUCTURES; SOLID-STATE STRUCTURES; ETHYLENE POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; X-RAY; OLEFIN POLYMERIZATION;
D O I：
10.1016/j.ccr.2024.215845
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chemistry of redox-active bis(imino)acenaphthenes (BIAN, R-bian) and metal complexes based on them has been a rapidly developing field since the 1990s. The key features of this class of compounds are their chemical stability and structural rigidity, which predisposes them to chelating metal ions; stereoelectronic tunability of R substituents and increased ability to accept electrons. The redox non-innocent behavior of BIAN is widely sought after in metal complex catalysis. Transition metal complexes with R-bian ligands are the most developed area. This review summarizes the data on the chemistry of BIAN complexes of d-block metals available up to 2023. Herein, we describe their preparation, structural features, redox behavior, magnetic and catalytic properties, as well as biological activity.
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页数：68
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共 361 条
  • [1] Coordination ability of N,N'-disubstituted 9,10-phenanthrenediimines
    Abakumov, G. A.
    Druzhkov, N. O.
    Kocherova, T. N.
    Kozhanov, K. A.
    Murugova, A. V.
    Egorova, E. N.
    [J]. DOKLADY CHEMISTRY, 2016, 467 : 109 - 112
  • [2] Organoelement chemistry: promising growth areas and challenges
    Abakumov, Gleb A.
    Piskunov, Alexandr V.
    Cherkasov, Vladimir K.
    Fedushkin, Igor L.
    Ananikov, Valentine P.
    Eremin, Dmitry B.
    Gordeev, Evgeniy G.
    Beletskaya, Irina P.
    Averin, Alexei D.
    Bochkarev, Mikhail N.
    Trifonov, Alexander A.
    Dzhemilev, Usein M.
    D'yakonov, Vladimir A.
    Egorov, Mikhail P.
    Vereshchagin, Anatoly N.
    Syroeshkin, Mikhail A.
    Jouikov, Viatcheslav V.
    Muzafarov, Aziz M.
    Anisimov, Anton A.
    Arzumanyan, Ashot V.
    Kononevich, Yuriy N.
    Temnikov, Maxim N.
    Sinyashin, Oleg G.
    Budnikova, Yulia H.
    Burilov, Alexander R.
    Karasik, Andrey A.
    Mironov, Vladimir F.
    Storozhenko, Pavel A.
    Shcherbakova, Galina I.
    Trofimov, Boris A.
    Amosova, Svetlana V.
    Gusarova, Nina K.
    Potapov, Vladimir A.
    Shur, Vladimir B.
    Burlakov, Vladimir V.
    Bogdanov, Vyacheslav S.
    Andreev, Maxim V.
    [J]. RUSSIAN CHEMICAL REVIEWS, 2018, 87 (05) : 393 - 507
  • [3] Mechanistic study of the [(dpp-bian)Re(CO)3Br] electrochemical reduction using in situ EPR spectroscopy and computational chemistry
    Abramov, Pavel A.
    Dmitriev, Alexey A.
    Kholin, Kirill V.
    Gritsan, Nina P.
    Kadirov, Marsil K.
    Gushchin, Artem L.
    Sokolov, Maxim N.
    [J]. ELECTROCHIMICA ACTA, 2018, 270 : 526 - 534
  • [4] Photophysical properties of platinum(II)-acetylide complexes: The effect of a strongly electron-accepting diimine ligand on excited-state structure
    Adams, Christopher J.
    Fey, Natalie
    Harrison, Zoe A.
    Sazanovich, Igor V.
    Towrie, Michael
    Weinstein, Julia A.
    [J]. INORGANIC CHEMISTRY, 2008, 47 (18) : 8242 - 8257
  • [5] Adams CJ, 2007, DALTON T, P4446, DOI 10.1039/b709252k
  • [6] First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
    Alig, Lukas
    Fritz, Maximilian
    Schneider, Sven
    [J]. CHEMICAL REVIEWS, 2019, 119 (04) : 2681 - 2751
  • [7] Alpha and beta diimine cobalt complexes in isoprene polymerization: a comparative study
    Alnajrani, Mohammed N.
    Alshmimri, Sultan A.
    Alsager, Omar A.
    [J]. RSC ADVANCES, 2016, 6 (114): : 113803 - 113814
  • [8] Molybdenum η3-allyl dicarbonyl complexes as a new class of precursors for highly reactive epoxidation catalysts with tert-butyl hydroperoxide
    Alonso, Joao C.
    Neves, Patricia
    Pires da Silva, Maria Joao
    Quintal, Susana
    Vaz, Pedro D.
    Silva, Carlos
    Valente, Anabela A.
    Ferreira, Paula
    Calhorda, Maria Jose
    Felix, Vitor
    Drew, Michael G. B.
    [J]. ORGANOMETALLICS, 2007, 26 (23) : 5548 - 5556
  • [9] Catalyst activity or stability: the dilemma in Pd-catalyzed polyketone synthesis
    Amoroso, Francesco
    Zangrando, Ennio
    Carfagna, Carla
    Mueller, Christian
    Vogt, Dieter
    Hagar, Mohamed
    Ragaini, Fabio
    Milani, Barbara
    [J]. DALTON TRANSACTIONS, 2013, 42 (40) : 14583 - 14602
  • [10] Accessing multiple polyethylene grades via a single redox-active olefin polymerization catalyst
    Anderson, W. Curtis, Jr.
    Park, Sang H.
    Brown, Lauren A.
    Kaiser, Jordan M.
    Long, Brian K.
    [J]. INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (07): : 1108 - 1112
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