Design of Bismuth-Based Electrocatalysts for Carbon Dioxide Electroreduction

被引：0

作者：

Wang, Xin ^{[1
]}

Mahbub, Muhammad Adib Abdillah ^{[1
]}

Das, Debanjan ^{[1
]}

Schuhmann, Wolfgang ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Fac Chem & Biochem, Analyt Chem Ctr Electrochem Sci CES, Univ Str 150, D-44780 Bochum, Germany

来源：

CHEMCATCHEM | 2024年 / 16卷 / 17期

基金：

欧洲研究理事会;

关键词：

bismuth-based catalysts; electrochemical CO2 reduction reaction; phase engineering; organic ligand modification; in situ characterization; ELECTROCHEMICAL REDUCTION; CO2; REDUCTION; FORMATE; COPPER;

D O I：

10.1002/cctc.202400601

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tuning the activity, selectivity, and stability of electrocatalysts for the electrochemical CO2 reduction reaction (eCO(2)RR) is of high interest. Among the multitude of possible eCO(2)RR products, formic acid/formate is not only of high industrial importance but even more importantly it can be obtained at nearly 100 % Faradaic efficiency if suitable catalysts are employed for the eCO(2)RR. Recently, two distinct strategies to modulate the eCO(2)RR over Bi-based catalysts, namely phase modulation and functionalization with organic ligands, have come to the fore. This concept paper aims to string them together to accelerate their exploitation to design sophisticated electrocatalysts for the eCO(2)RR.

引用

页数：7

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