Photovoltage from ferroelectric domain walls in BiFeO3 (vol 102, 081304, 2020)

被引:0
作者
Korbel, Sabine
Sanvito, Stefano
机构
基金
爱尔兰科学基金会;
关键词
D O I
10.1103/PhysRevB.110.039902
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the original article a mistake in the methodology led to an incorrect prediction of exciton delocalization below a critical exciton density. This unrealistic delocalized exciton state yielded a sizable domain-wall photovoltage. When done correctly, the simulations yield self-trapped (localized) excitons at all considered exciton densities, without any evidence for a transition to a delocalized exciton. This realistic self-trapped exciton state yields only a negligible domain-wall photovoltage. The original conclusion that ferroelectric domain walls could be responsible for the measured photovoltage if carrier lifetime and diffusion length are higher than expected is incorrect. Correct is: The domain-wall photovoltage in BiFeO3 is much too small to explain the measured photovoltage. The original analysis is meaningful for ferroelectrics without carrier self-trapping, not for BiFeO3.
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[1]  
Sabine Korbel., 2020, Phys. Rev. B., V102